| 1360571-88-5

• CAS: 1360571-88-5
• 化学式: C₃₉H₄₅Cl₄N₅O₄Pt₂
• 分子量: 1179.79
• InChiKey: KXFZHASCYDRIGV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 potassium tetrachloroplatinate(II) 、 2,6-Bis[2-[3-[2-(4-methylpyridin-2-yl)pyridin-4-yl]propoxy]ethoxymethyl]pyridine 以 盐酸 、 水 、 丙酮 为溶剂， 以50.6%的产率得到
  参考文献：
  名称：

  Cu(II), Ag(I) and Pt(II) bipyridine oligomer metallomacrocycles that function as efficient host complexes for the encapsulation of alkali ion guests

  摘要：

  Two open-chain bipyridine oligomers (1 and 2) were coordinated to Cu(II) (3 and 4) and Ag(I) (5 and 6) metal centers producing the corresponding closed-pocket monometallic macrocycles. The oligomers were also coordinated to two Pt(II) dichloride moieties (7 and 8) producing the bimetallic oligomeric complexes. The metallated complexes were more efficient alkali ion extractors than the free ligands and they displayed unique ion selectivities based on the nature of the metallomacrocycle that was formed. The largest monometallic Ag(I) system (6) displayed the highest extraction efficiency (EE) values for all ions (Na+, K+, and Cs+) with an ion selectivity order of Na+ > K+ > Cs+. The bimetallic Pt(II) systems (7 and 8) were less efficient overall than the monometallic complexes at extracting ions, but displayed greater ion selectivity. The ion selectivity order for these complexes was Cs+ > K+ > Na+. The uncomplexed host transition metal systems were characterized using H-1 NMR spectroscopy and MALDI-TOF mass spectrometry and the ion-encapsulated host-guest systems were characterized using ESI and MALDI-TOF mass spectrometry and UV-Vis spectroscopy. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.11.050