[bis(cyclopentadienyldimethylmethyl)cyclohexylphosphino]ferrocenophane | 864499-42-3

• 英文名称: [bis(cyclopentadienyldimethylmethyl)cyclohexylphosphino]ferrocenophane
• 英文别名: [Fe((η(5)-C5H4)CMe2)2PCy]
• CAS: 864499-42-3
• 化学式: C₂₂H₃₁FeP
• 分子量: 382.309
• InChiKey: MODYWDRYYSNVLP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (1-methyl-1-cyclohexylphosphinoethyl)cyclopentadienyllithium 、 dilithiumcyclohexylphosphinobis(dimethylmethylcyclopentadienide) 、 iron(II) chloride 以 四氢呋喃 为溶剂， 以48%的产率得到[bis(cyclopentadienyldimethylmethyl)cyclohexylphosphino]ferrocenophane
  参考文献：
  名称：

  Novel [3]ferrocenophanes: Syntheses, redox properties and molecular structures of [Fe{(η5-C5H4)CMe2}2PR] (R=Ph, Cy)

  摘要：

  6,6-Dimethylfulvene reacts with Li2PR to give Li-2[{(C5H4)CMe2}(2)PR] [R =Ph (1), Cy (2)]. The ferrocenophanes [Fe{(eta(5)- C5H4)CMe2}(2)PR] [R = Ph (3), Cy (4)] are obtained in good yield from the lithium reagents I and 2 and FeCl2. Compounds 3 and 4 were characterised spectroscopically (H-1, C-13, P-31, IR, MS), and by crystal structure determination. Electrochemical investigation shows that 3 undergoes a one-electron oxidation in CH2Cl2 solution, which is chemically reversible on the short timescale of cyclic voltammetry, but in the longer time frame of macroelectrolysis the monocation [3](+) forms a new species that we tentatively assign as [Fe{(eta(5)-C5H4)CMe2}(2)P(O)Ph]. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.04.026