((η5-C5Me5)Fe)2(.mu-hydride)(hydride)bis(μ-diphenylphosphido)) | 307500-64-7

• 英文名称: ((η5-C5Me5)Fe)2(.mu-hydride)(hydride)bis(μ-diphenylphosphido))
• CAS: 307500-64-7
• 化学式: C₄₄H₅₂Fe₂P₂
• 分子量: 754.538
• InChiKey: AQZNCQWPJFQDLU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  ((η5-C5Me5)Fe)2(μ-hydride)2(μ-η2:η2-di-tert-butylsilane) 、 二苯基膦 以 not given 为溶剂， 以99%的产率得到((η5-C5Me5)Fe)2(.mu-hydride)(hydride)bis(μ-diphenylphosphido))
  参考文献：
  名称：

  {(η⁵-C₅Me₅)Fe}₂(μ-H)₂(μ-η²:η²-H₂Si^tBu₂), a Versatile Precursor for Bimetallic Active Species

  摘要：

  Reaction of {(eta (5)-C5Me5)Fe}(2)(mu -H)(4) with (BU2)-B-t- SiH2 provides the first dinuclear iron mu -silane complex, {(eta (5)-C5Me5)Fe}(2)(mu -H)(2)(mu-eta (2):eta (2)-H-2-(SiBu2)-Bu-t), in which two Si-H sigma -bonds are coordinated to two iron centers. The coordinated Si-H bond is readily cleaved and the mu -silane ligand is eliminated to give a dinuclear iron active-species which reacts in situ with organic substrates.

  DOI：

  10.1021/om0101238