[bis(2,2'-bipyridine)bis(hexafluoroacethylacetonate)lead(II)] | 868049-06-3

• 英文名称: [bis(2,2'-bipyridine)bis(hexafluoroacethylacetonate)lead(II)]
• CAS: 868049-06-3
• 化学式: C₃₀H₁₈F₁₂N₄O₄Pb
• 分子量: 933.678
• InChiKey: RGBYCWHSAIVRTC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 lead(II) nitrate 、 六氟乙酰丙酮 在 sodium hydroxide 作用下， 以 水 、 乙腈 为溶剂， 生成 [bis(2,2'-bipyridine)bis(hexafluoroacethylacetonate)lead(II)]
  参考文献：
  名称：

  Fluorous interactions in complexes of lead(II) hexafluoroacetylacetonate

  摘要：

  Structure determinations for 2,2'-bipyridine and 1,10-phenanthroline adducts of lead(II) hexafluoroacetylacetonate, [Pb(biPY)(2)(hfacaC)(2)- (1), [Pb(bipy)(hfacac)(2)] (2), and [Pb(phen)(hfacac)(2)] (3), show that the balance of intermolecular forces within the lattices is seemingly sensitive to the adduct stoichiometry but not to the nature of the heteroaromatic base. In 3, a structure, in which there is an apparent preference for CF/aromatic interactions over separate CF/CF and aromatic/aromatic interactions, is essentially identical at both 120 and 293 K. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.015