| 151920-98-8

• CAS: 151920-98-8
• 化学式: BrClO
• 分子量: 131.356
• InChiKey: SLLIQRFSMNTOID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  溴 、 氯 、 臭氧 以 gaseous matrix 为溶剂， 生成
  参考文献：
  名称：

  Experimental and Theoretical Study of the XYO (X, Y = Cl, Br) Light-Induced Interconversion in Argon Matrix

  摘要：

  The complex ClBrO has been generated in argon matrix by photolysis of the O-3:BrCl complex and has been characterized by its Fourier-transform IR spectrum. Wavelength dependence of ClBrO photochemistry has been determined in the range from 317 to 870 nm by using laser irradiations and in the frequency region of a Nernst globar. Visible irradiation between 633 and 700 nm transforms ClBrO into BrClO and that above 700 nm continues the transformation into BrOCl. Reverse photoisomerization of BrOCl into ClBrO or BrClO was not observed. BrClO but not ClBrO is sensitive to IR irradiation. Calculations are combined with experimental observations to present a model for the photochemical isomerization of ClBrO and a comparison with related Cl2O and Br2O isomerizations.

  DOI：

  10.1021/jp980952f

文献信息

• Matrix reaction of ozone with Cl2 and Br2. FTIR identification of BrC10 and ClBrO species
  作者：L. Schriver-Mazzuoli、O. Abdelaoui、C. Lugez、A. Schriver

  DOI：10.1016/0009-2614(93)85676-f

  日期：1993.11

  Photolysis of argon samples containing Cl2, Br2, O3 with 800-360 nm irradiation produced new absorptions at 940.9-932.7 and 818.9-817.5 cm−1, which were assigned to the new BrClO and ClBrO species. Formation of these species proceeds through photodissociation of BrCl: O3 and ClBr: O3 complexes. Photolysis of ClBrO molecules above 400 nm produced BrCl species.

  含Cl 2，Br 2，O 3的氩气样品在800-360 nm照射下发生光解，在940.9-932.7和818.9-817.5 cm -1处产生新的吸收，这些吸收被指定为新的BrClO和ClBrO种类。这些物质的形成通过BrCl：O 3和ClBr：O 3络合物的光解而进行。ClBrO分子在400 nm以上的光解产生BrCl物质。