| 176697-22-6

• CAS: 176697-22-6
• 化学式: C₃₄H₄₄Al₂N₂O₂
• 分子量: 566.699
• InChiKey: FNHHXGSLSMCORK-DVDRBMSDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三甲基铝 、 (betaR)-beta-氨基-gamma-苯基-苯丙醇 以 甲苯 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of Chiral Amine Alcohol Complexes of Aluminum

  摘要：

  The syntheses and full characterization of chiral amine alcohol complexes of aluminum are reported. These complexes are of two general formulae, those resulting from the reaction of 1 equiv of an aluminum reagent with an amine alcohol, [AA-AlR(2)](2) (where AA = phenylglycinol (PGly), R = Me (1), Et (2), SiMe(3) (3); phenylalaninol (PAla), R = Me (4), Et (5), SiMe(3) (6); and diphenylalaninol (DPAla), R = Me (7), Et (8), SiMe(3) (9), and the series resulting from the reaction of 2 equiv of AlMe(3) with an amine alcohol, AA(AlMe(2))-AlMe(3) (where AA = PGly (10), PAla (11), and DPAla (12)). These compounds significantly increase the number of chiral group 13 complexes that have been reported in the literature. Additionally, the crystal structures of 5, 6, and 11 have been obtained.

  DOI：

  10.1021/om9509913