| 25534-93-4

• CAS: 25534-93-4
• 化学式: Cl₄Zn*H₁₈N₆Ru
• 分子量: 410.455
• InChiKey: FCXMDSQTPCYWAT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 在 aq. bromine 作用下， 以 水 为溶剂， 生成 pentaamminechlororuthenium(III) dichloride
  参考文献：
  名称：

  Double complex salts [M(NH3)5Cl][M′Br4] (M = Rh, Ir, Co, Cr, Ru; M′ = Pt, Pd): Synthesis, x-ray diffraction characterization, and thermal properties

  摘要：

  Double complex salts (DCSs) with [M(NH3)(5)Cl](2+) (M = Rh, Ir, Co, Cr, Ru) cations and [PtBr4](2-) anions were prepared in high yields. The salts were two-phase mixtures of the anhydrous and monohydro DCSs. Anhydrous analogues containing [PdBr4](2-) anions with M = Cr or Ru were synthesized. All the compounds were characterized using a set of physicochemical methods. The crystal structure of chloropentaamminechromium(III) tetrabromopalladate(II) was solved: space group Pnma, Z = 4, a = 17.068(2) angstrom, b = 8.315(12) angstrom, c = 9.653(14) angstrom. The [M(NH3)(5)Cl][M'X-4] (M = Rh, Ir, Co, Cr, Ru; M' = Pd, Pt; X = Cl, Br) compounds were shown to be isostructural. The [M(NH3)(5)Cl][PtBr4] center dot H2O monohydrates are isostructural to the [M(NH3)(5)Cl][PdCl4] center dot H2O monohydrates (space group P2(1)/c, z = 4). The properties of the compounds were comparatively analyzed. The tendencies of the thermal stability of the complexes were elucidated. The thermolysis products of the double complex salts obtained under a helium or hydrogen atmosphere were studied.

  DOI：

  10.1134/s0036023606020070
• 作为产物：
  描述：

  盐酸 、 三氯化钌 、 锌 、 zinc(II) chloride dihydrate 、 ammonium hydroxide 以 水 为溶剂， 生成
  参考文献：
  名称：

  Double complex salts [M(NH3)5Cl][M′Br4] (M = Rh, Ir, Co, Cr, Ru; M′ = Pt, Pd): Synthesis, x-ray diffraction characterization, and thermal properties

  摘要：

  Double complex salts (DCSs) with [M(NH3)(5)Cl](2+) (M = Rh, Ir, Co, Cr, Ru) cations and [PtBr4](2-) anions were prepared in high yields. The salts were two-phase mixtures of the anhydrous and monohydro DCSs. Anhydrous analogues containing [PdBr4](2-) anions with M = Cr or Ru were synthesized. All the compounds were characterized using a set of physicochemical methods. The crystal structure of chloropentaamminechromium(III) tetrabromopalladate(II) was solved: space group Pnma, Z = 4, a = 17.068(2) angstrom, b = 8.315(12) angstrom, c = 9.653(14) angstrom. The [M(NH3)(5)Cl][M'X-4] (M = Rh, Ir, Co, Cr, Ru; M' = Pd, Pt; X = Cl, Br) compounds were shown to be isostructural. The [M(NH3)(5)Cl][PtBr4] center dot H2O monohydrates are isostructural to the [M(NH3)(5)Cl][PdCl4] center dot H2O monohydrates (space group P2(1)/c, z = 4). The properties of the compounds were comparatively analyzed. The tendencies of the thermal stability of the complexes were elucidated. The thermolysis products of the double complex salts obtained under a helium or hydrogen atmosphere were studied.

  DOI：

  10.1134/s0036023606020070

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 165, page 450 - 452
  作者：

  DOI：——

  日期：——
• Lever, F. M.; Powell, A. R., Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1969, p. 1477 - 1482
  作者：Lever, F. M.、Powell, A. R.

  DOI：——

  日期：——
• Lever, F. M.; Powell, A. R., Intern. Conf. Co-ord. Chem., London 1959, Lectures Abstr., S. 135/136
  作者：Lever, F. M.、Powell, A. R.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 162, page 443 - 446
  作者：

  DOI：——

  日期：——
• Harris, R. O., Thesis Toronto, Ont., 1963, S. 73
  作者：Harris, R. O.

  DOI：——

  日期：——