| 143331-91-3

• CAS: 143331-91-3
• 化学式: C₂₄H₂₈Cl₂Cu₂Mo₂N₂O₁₂
• 分子量: 926.371
• InChiKey: DJCSHHLUQKQMGU-KXMLSBJZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 2,2'-bipyridyl 作用下， 以 乙腈 为溶剂， 以25%的产率得到
  参考文献：
  名称：

  Synthesis, characterisation and crystal structure of molybdenum and molybdenum–copper hydroxy-rich Schiff-base complexes

  摘要：

  The reaction of hydroxy-rich Schiff bases [H(3)L = XC(6)H(3)(OH) CH=NC(R)(CH2OH)(2) where X = H, 5-CI or 5-Br and R = Me or Et] with [MoO2(acac)(2)] (acac = acetylacetonate) gave mononuclear complexes [MoO2(HL)(MeOH)]. The complexes were characterised by spectroscopic methods and by a single-crystal structure determination. Reaction of the mononuclear complexes with Ph(2)PCH(2)PPh(2) in methanol or acetonitrile led to five-co-ordinate polymeric compounds of the type [MoO(L)](n) in which the fifth position of the distorted square pyramid is occupied by the oxygen atom of a CH2O- moiety of a neighbouring repeat unit. The complex [MoO2(HL(3))(MeOH)][H(3)L(3)=2-(5-chlorosalicylideneamino)-1 ,3-dihydroxy-2-methylpropane] reacted with Cu(O(2)CMe)(2) in methanol-acetonitrile to yield the mixed-metal cluster [Cu(2)Mo(2)O(4)L(2)(3)(OMe)(2)] with a Cu2Mo2O4 cubane-like core. Reflux of this complex with an excess of 2,2'-bipyridine in acetonitrile yielded pale blue-green crystals of the tetranuclear cluster [CuMo3O8(HL(3))(2)(bipy)(2)] the structure of which has been determined by X-ray crystallography. The molybdenum part may be described in terms of three ore-bridged centres, one tetraoxomolybdate [MoO4](2-) and two six-co-ordinated MoO2(Schiff base) moieties. The magnetic properties of this compound have been studied in the temperature range 5-300 K.

  DOI：

  10.1039/dt9950002591
• 作为产物：
  描述：

  bis(acetylacetonato)dioxidomolybdenum(VI) 、 tetrakis(acetato)diaquadicopper(II) 、 2-氨基-2-甲基-1,3-丙二醇 、 5-氯代水杨醛 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Kessissoglou, Dimitris P.; Raptopoulou, Catherine P.; Bakalbassis, Evangelos G., Inorganic Chemistry, 1992, vol. 31, # 21, p. 4339 - 4345

  摘要：

  DOI：