(FeC5H5C5H3PPh2)2PC6H5 | 1094756-49-6

• 英文名称: (FeC5H5C5H3PPh2)2PC6H5
• CAS: 1094756-49-6
• 化学式: C₅₀H₄₁Fe₂P₃
• 分子量: 846.491
• InChiKey: UTQFMFXQWKLIGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  正丁基锂 、 (S,S)-(FeC5H5C5H3Br)2PC6H5 、 二苯基氯化膦 在 2,2,6,6-四甲基哌啶 作用下， 以 四氢呋喃 为溶剂， 生成 (FeC5H5C5H3PPh2)2PC6H5
  参考文献：
  名称：

  The conversion of 1,1′-dibromoferrocene to 1,2-dibromoferrocene: The ferrocene-chemist’s dream reaction

  摘要：

  The conversion of 1,1'-dibromoferrocene to a range of 2-substituted bromoferrocenes is described. The products are useful in the preparation of a wide number of 1,2-disubstituted ferrocenes. This includes the preparation of 1,2-dibromoferrocene and 2-(diisopropylphosphino)bromoferrocene in what is a clean and simple synthesis. The synthesis may be carried out on a large scale and for the first time produces multigram quantities of these important precursor compounds. In addition the synthetic procedure may be modified to produce a new family of ferrocene-based tris-phosphine ligands such as bis(2-diphenylphosphinoferrocenyl)phenylphosphine. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.09.020