| 1194450-20-8

• CAS: 1194450-20-8
• 化学式: C₆₀H₃₄FeN₄O₂S₆*F₆P
• 分子量: 1236.16
• InChiKey: UGCAXSFMVFNYDF-GEHZQPGBSA-L

反应信息

• 作为反应物：
  描述：

  在 (CH₃CH₂CH₂CH₂)4NPF₆ 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable-Temperature Electrical Conductivity

  摘要：

  We describe the multistep synthesis of a new terthienyl-substituted QsaIH ligand and an iron(3+) spin-crossover complex (1) containing this ligand, which electropolymerizes to produce a hybrid-conducting metallopolymer film (poly1). Variable-temperature magnetic susceptibility measurements demonstrate that spin-crossover is operative in the polymer film, and resistivity measurements on indium-tin oxide coated glass slides containing the polymer film exhibit intriguing temperature-dependent profiles.

  DOI：

  10.1021/ic9015542
• 作为产物：
  描述：

  iron(III) chloride hexahydrate 、 sodium hexaflorophosphate 、 以 水 为溶剂， 生成
  参考文献：
  名称：

  Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable-Temperature Electrical Conductivity

  摘要：

  We describe the multistep synthesis of a new terthienyl-substituted QsaIH ligand and an iron(3+) spin-crossover complex (1) containing this ligand, which electropolymerizes to produce a hybrid-conducting metallopolymer film (poly1). Variable-temperature magnetic susceptibility measurements demonstrate that spin-crossover is operative in the polymer film, and resistivity measurements on indium-tin oxide coated glass slides containing the polymer film exhibit intriguing temperature-dependent profiles.

  DOI：

  10.1021/ic9015542