| 849240-32-0

• CAS: 849240-32-0
• 化学式: CF₃O₃S*C₂₃H₂₇N₂O₂Ru
• 分子量: 613.62
• InChiKey: DCUHXXFCDQVNPJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 以 水 为溶剂， 生成 [η6-C6Me6)(bipy)Ru(H2O)](OTf)2 、 草氨酸
  参考文献：
  名称：

  Accelerating Effect of a Proton on the Reduction of CO₂ Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex

  摘要：

  A water-soluble hydride complex [(eta6-C6Me6)RuII(bpy)H]+ {1, bpy = 2,2'-bipyridine} serves as a robust reducing agent for the reduction of CO2 in water in a pH range of about 3-5 at ambient temperature under stoichiometric conditions. The structure of 1 was unequivocally determined by X-ray analysis. The mechanism of acid-catalyzed reduction of CO2 promoted by 1 in water under acidic conditions is disclosed.

  DOI：

  10.1021/ja036117f
• 作为产物：
  描述：

  [Ru(η6-C6Me6)(bpy)H](trifluoromethanesulfonate) 、 二氧化碳 、 水 以 水 为溶剂， 生成
  参考文献：
  名称：

  Accelerating Effect of a Proton on the Reduction of CO₂ Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex

  摘要：

  A water-soluble hydride complex [(eta6-C6Me6)RuII(bpy)H]+ {1, bpy = 2,2'-bipyridine} serves as a robust reducing agent for the reduction of CO2 in water in a pH range of about 3-5 at ambient temperature under stoichiometric conditions. The structure of 1 was unequivocally determined by X-ray analysis. The mechanism of acid-catalyzed reduction of CO2 promoted by 1 in water under acidic conditions is disclosed.

  DOI：

  10.1021/ja036117f