(2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine+H)[AuCl4] | 1258698-23-5

• 英文名称: (2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine+H)[AuCl4]
• CAS: 1258698-23-5
• 化学式: AuCl₄*C₁₄H₁₃N₄
• 分子量: 576.063
• InChiKey: ZPYZOJRXOYTBOO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  5.26
• 重原子数：
  23.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  43.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  2-{[4-phenyl-1H-1,2,3-triazol-1-yl]methyl}pyridine 、 potassium tetrachloroaurate(III) dihydrate 在 potassium tetrachloroaurate(III) dihydrate 作用下， 以 甲醇 、 水 、 丙酮 为溶剂， 反应 6.0h， 生成 (2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine+H)[AuCl4]
  参考文献：
  名称：

  Synthesis and characterization of novel gold(III) complexes with polydentate N-donor ligands based on the pyridine and triazole heterocycles

  摘要：

  The coordination chemistry towards the Au(III) metal centre of the pyridine-triazole ligands 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Ph)) and 2-[(4-pentyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Pent))has been explored and complexes having formulae AuCl3(pytz(Ph)) (1(Ph)) and AuCl3(pytz(Pent)) (1(Pent)) have been isolated and characterised. Reaction of 1(Ph) with AgClO4 allowed the preparation of the compound [AuCl2(pytz(Ph))](ClO4) (2(Ph)). Reaction of 1(Ph) and 1(Pent) with K[AuCl4]center dot 2H(2)O led to the formation of the salts [Hpytz(Ph)][AuCl4] (3(Ph)) and [Hpytz(Pent)][AuCl4] (3(Pent)). (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.04.015

文献信息

• Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3-triazole “click” ligands: Synthesis, properties and X-ray structures
  作者：Kelly J. Kilpin、James D. Crowley

  DOI：10.1016/j.poly.2010.08.021

  日期：2010.10

  The synthesis and characterization of palladium(II) and platinum(II) complexes of isomeric bidentate 2-pyridyl-1,2,3-triazole "click" ligands is reported. The complexes have been fully characterized by elemental analysis, HRESI-MS, IR, UV-Vis, H-1 and C-13 NMR spectroscopy. Additionally, the molecular structures of the Pd(II) and Pt(II) complexes of the 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand are confirmed by X-ray crystallography. Solution studies indicate the 2-(1-benzyl-1H-1,2,3-triazol-4-yl)pyridine ligand forms more stable complexes with Pd(II) and Pt(II) than the isomeric 2[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand. (C) 2010 Elsevier Ltd. All rights reserved.