| 156056-21-2

• CAS: 156056-21-2
• 化学式: C₂₂H₄₇ClO₂OsP₂
• 分子量: 631.215
• InChiKey: ULSQDUMCZIWKML-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代氯仿 为溶剂， 生成 、
  参考文献：
  名称：

  Reactions of OsHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of (Vinylcarbene)osmium(II) Complexes

  摘要：

  The monohydride complex OsHCl(CO)(PiPr3)2 (1) reacts with 2-propyn-1-ol to give the vinyl compounds(CH=CHCH2OH)CI(CO)(PiPr3)2(2a). The reaction of 1 with 1-phenyl-2-propyn-1-ol leads to a mixture of products, from which the complexes OSCl2(=CHCH=CHPh)(CO)-(PiPr3)2 (3a) and 6s(CHCHC(6)Ph)Cl(CO)(PiPr3)2 (4a) were separated. The molecular structures of complexes 3a and 4a were determined by X-ray crystallography. Crystals of 3a are monoclinic, space group P2(1)/c, with unit cell dimensions a = 15.671(3) angstrom, b = 12.507(2) angstrom, c = 16.632(3) angstrom, and beta = 108.95(1-degrees). The structure was refined to the R and R(w) values 0.0202 and 0.0239 on 5080 observed data. The coordination around the osmium atom can be described as a distorted octahedron with the two triisopropylphosphine ligands occupying trans positions; the perpendicular plane is defined by the vinylcarbene and a carbonyl ligand, mutually cis disposed, and by two chloride atoms. Crystals of 4a are orthorhombic, space group P2(1)2(1)2(1), with a = 8.797(1) angstrom, b = 15.268(2) angstrom and c = 22.275(3) angstrom. The structure was refined to the R and R(w) values 0.0198 and 0.0223 on 5532 reflections. The osmium coordination environment can also be rationalized as a distorted octahedron with the two phosphine ligands disposed mutually trans. The remaining coordination sites of the octahedron are occupied by the carbonyl ligand, the chloride atom, and the chelate CHCHC(O)Ph ligand. The reaction of 1 with 1,1-diphenyl-2-propyn-1-ol also leads to a mixture of products, from which the complex OSCl2(=CHCH=CPh2)-(CO)(P(i)Pr3)2 (3b) was isolated and characterized.

  DOI：

  10.1021/om00017a025
• 作为产物：
  描述：

  bis(triisopropylphosphane)chloro(hydrido)carbonylosmium(II)(PiPr3)2 、 2-丙炔-1-醇 以 甲苯 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Reactions of OsHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of (Vinylcarbene)osmium(II) Complexes

  摘要：

  The monohydride complex OsHCl(CO)(PiPr3)2 (1) reacts with 2-propyn-1-ol to give the vinyl compounds(CH=CHCH2OH)CI(CO)(PiPr3)2(2a). The reaction of 1 with 1-phenyl-2-propyn-1-ol leads to a mixture of products, from which the complexes OSCl2(=CHCH=CHPh)(CO)-(PiPr3)2 (3a) and 6s(CHCHC(6)Ph)Cl(CO)(PiPr3)2 (4a) were separated. The molecular structures of complexes 3a and 4a were determined by X-ray crystallography. Crystals of 3a are monoclinic, space group P2(1)/c, with unit cell dimensions a = 15.671(3) angstrom, b = 12.507(2) angstrom, c = 16.632(3) angstrom, and beta = 108.95(1-degrees). The structure was refined to the R and R(w) values 0.0202 and 0.0239 on 5080 observed data. The coordination around the osmium atom can be described as a distorted octahedron with the two triisopropylphosphine ligands occupying trans positions; the perpendicular plane is defined by the vinylcarbene and a carbonyl ligand, mutually cis disposed, and by two chloride atoms. Crystals of 4a are orthorhombic, space group P2(1)2(1)2(1), with a = 8.797(1) angstrom, b = 15.268(2) angstrom and c = 22.275(3) angstrom. The structure was refined to the R and R(w) values 0.0198 and 0.0223 on 5532 reflections. The osmium coordination environment can also be rationalized as a distorted octahedron with the two phosphine ligands disposed mutually trans. The remaining coordination sites of the octahedron are occupied by the carbonyl ligand, the chloride atom, and the chelate CHCHC(O)Ph ligand. The reaction of 1 with 1,1-diphenyl-2-propyn-1-ol also leads to a mixture of products, from which the complex OSCl2(=CHCH=CPh2)-(CO)(P(i)Pr3)2 (3b) was isolated and characterized.

  DOI：

  10.1021/om00017a025