| 401513-30-2

• CAS: 401513-30-2
• 化学式: C₄₀H₅₀FeS₂Si₂
• 分子量: 706.987
• InChiKey: NEHBKFHTBUURNM-FAVHNTAZSA-N

反应信息

• 作为产物：
  描述：

  劳森试剂 、 cyclopenta-2,4-dien-1-yl-[dimethyl(phenyl)silyl]methanone;iron(2+) 、 2,3-二甲基-1,3-丁二烯 以 四氢呋喃 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Synthesis and reactivity of achiral and of a novel planar chiral thioferrocenoylsilanes

  摘要：

  The reactions of thioferrocenoylsilanes with organolithium reagents, dienes and reducing agents which afford alpha -silyl sulphides, dihydrothiopyranes and alpha -silyl ferrocenyl thiols, respectively, have been investigated. alpha -Silyl sulphides were further functionalised through carbodesilylation with aldehydes. We also report the synthesis of a new planar chiral thioferrocencylsilane that gave good diastereomeric excess in the reaction with t-butyllithium, lithium lutidine and 2,3-dimethylbuta-1,3-diene. The 1,1'-bis-thioferrocenoylsilane, too unstable to be isolated, was trapped in situ with dienes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00944-5