η2-(cyclohexene)pentacarbonylchromium(0) | 165270-85-9

• 英文名称: η2-(cyclohexene)pentacarbonylchromium(0)
• 英文别名: (cyclohexene)pentacarbonylchromium
• CAS: 165270-85-9
• 化学式: C₁₁H₁₀CrO₅
• 分子量: 274.193
• InChiKey: HCCRIBCYAJYILJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  六羰基铬 、 环己烯 以 四氢呋喃 为溶剂， 生成 η2-(cyclohexene)pentacarbonylchromium(0)
  参考文献：
  名称：

  摘要：

  Depending on the reactant ratio and order of their mixing, reactions of dialkyl hydrogen phosphite with alkenes in the presence of catalytic amounts of homoligand carbonyl complexes of iron or chromium subgroup metals yield phosphonates by two pathways: reaction of dialkyl hydrogen phosphite with pi -coordinated alkene and addition to alkene of the product of reaction of dialkyl hydrogen phosphite with the transition metal carbonyl. The products of reactions of Fe(CO)(5) and W(CO)(6) with dialkyl hydrogen phosphites contain the phosphorus-metal bond.

  DOI：

  10.1023/a:1012352900754