Novel η2-ring edge coordination in the triphosphaferrocene complex [Fe(η5-C5H5)(η5-P3C2tBu2)Rh(η5-C5Me5)CO]
摘要:
Single-crystal X-ray diffraction studies on the triphosphaferrocene [Fe(eta(5)-C5H5)(eta(5)P(3)C(2)'Bu-2)] and its [Rh(eta(5)-C5Me5)CO] complex reveal an unusual eta(2)-ring edge coordination mode in the latter resulting in a significant elongation of the triphosphacyclopentadienyl ring P-P bond. (C) 1999 Elsevier Science S.A. All rights reserved.