(η6-p-cymene)Ru(II)Cl(OC6H4-CH2NHC6H4-o-OMe) complex | 388110-63-2

• 英文名称: (η6-p-cymene)Ru(II)Cl(OC6H4-CH2NHC6H4-o-OMe) complex
• CAS: 388110-63-2
• 化学式: C₂₄H₂₈ClNO₂Ru
• 分子量: 499.015
• InChiKey: OUQFCPWULNJDDA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(p-cymene)ruthenium(II) dimer 、 2-[[(2-甲氧基苯基)氨基]甲基]-苯酚 在 Na₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 生成 (η6-p-cymene)Ru(II)Cl(OC6H4-CH2NHC6H4-o-OMe) complex
  参考文献：
  名称：

  Transfer hydrogenation of acetophenone promoted by (arene)ruthenium(II) reduced Schiff base complexes: an X-ray structure of [(η6-p-cymene)RuCl(OC6H4-2-CH2NHC6H4-p-Me)]

  摘要：

  Arene ruthenium(II) reduced Schiff base complexes of formulation [(eta (6)-p-cymene)RuCl(L-n)] (1-5, n = 1-5) were prepared by reacting [(eta (6)-p-cymene)RuCl2](2) with HLn in the presence of sodium carbonate in CH2Cl2. The complexes contain an eta (6)-p-cymene group, a chloride and a bidentate chelating N,O-donor ligand. The molecular structure of [(eta (6)-p-cymene)RuCl(OC6H4-2-CH2NHC6H4-p-Me)] (1) has been determined by X-ray crystallography. The complexes are found to be catalytically active for transfer hydrogenation of acetophenone to (+/- )1-phenylethanol in the presence of KOH and isopropanol showing percent conversion of 98 with the catalysts having a bulky substituent adjacent to the O- and N-donor sites of the auxiliary ligand. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(01)00894-4