2,4-diferrocenylthiazole | 867197-89-5

• 英文名称: 2,4-diferrocenylthiazole
• CAS: 867197-89-5
• 化学式: C₂₃H₁₉Fe₂NS
• 分子量: 453.171
• InChiKey: RXDZPFNHZNVRMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-chloro-1-ferrocenylethanone 、 ferrocenecarbothioamide 在 K₂CO₃ 作用下， 以 甲苯 为溶剂， 以74%的产率得到2,4-diferrocenylthiazole
  参考文献：
  名称：

  Ferrocenecarbothioamide and N-ethoxycarbonylferrocenecarbothioamide: Synthesis, structure and application in synthesis of 2,4-diferrocenylthiazole

  摘要：

  Ferrocenecarbothioamide (1) and its N-ethoxycarbonyl derivative (2) were synthesised by a Friedel-Crafts type reaction of ferrocene with potassium thiocyanate and ethoxycarbonyl isothiocyanate, respectively, in a strongly acidic medium. The X-ray structure of I was determined and shows conjugation between the ferrocene moiety and the thioamido group. Compound I reacts with chloroacetylferrocene affording 2,4-diferrocenylthiazole, whose structure was determined by X-ray diffraction and electronic properties studied by cyclic voltammetry. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.037