[Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4) | 1193781-96-2

• 英文名称: [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4)
• 英文别名: [Ru(tpy)(bpy)(CF3SO3)](B(C6H3(CF3)2)4)
• CAS: 1193781-96-2
• 化学式: C₂₆H₁₉F₃N₅O₃RuS*C₃₂H₁₂BF₂₄
• 分子量: 1502.82
• InChiKey: OPFJNEIQSLGAHR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate dihydrate 、 [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4) 、 N,N-二甲基甲酰胺 以 dimethylformamide 为溶剂， 以89%的产率得到[Ru(tpy)(bpy)(DMF)](B(C6H3(CF3)2)4)2
  参考文献：
  名称：

  Quantitative Photochemical Formation of [Ru(tpy)(bpy)H]⁺

  摘要：

  Quantitative photochemical production of [Ru(tpy)(bpy)H](+) (Ru-H+) was achieved by irradiation of [Ru(tpy)(bpy)(DMF)](2+) (Ru-DMF2+; DMF = N,N-dimethylformamide) in a tetrahydrofuran (THF) solution containing excess triethylamine (NEW. The mechanism of the Ru-H+ formation was investigated in detail. A photochemical ligand substitution reaction of Ru-DMF2+ in THF proceeded to give [Ru(tpy)(bpy)(THF)](2+) (Ru-THF2+) with a quantum yield of (7.6 +/- 0.7) x 10(-2). In the presence of NEt3, a similar photochemical ligand substitution reaction also proceeded quickly, but the products were an equilibrium mixture of Ru-THF2+ and [Ru(tpy)(bpy)(NEt3)](2+) (Ru-NEt32+) with a considerable amount of Ru-H+ even in the first stage of the photochemical reaction. The equilibrium constant between Ru-THF2+ and Ru-NEt32+ was determined as 6.9 +/- 2.1. Irradiation to Ru-NEt32+ gave Ru-H+ with a quantum yield of (9.1 +/- 0.5) x 10(-3). An important intermediate, Ru-NEt32+, was isolated, and its properties were investigated in detail.

  DOI：

  10.1021/ic901080r
• 作为产物：
  描述：

  [RuCl(2,2':6':2''-terpyridine)(2,2'-bipyridine)](B(3,5-bis(trifluoromethyl)phenyl)4) 、 silver trifluoromethanesulfonate 以 CH₂Cl₂ 为溶剂， 以80%的产率得到[Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4)
  参考文献：
  名称：

  Quantitative Photochemical Formation of [Ru(tpy)(bpy)H]⁺

  摘要：

  Quantitative photochemical production of [Ru(tpy)(bpy)H](+) (Ru-H+) was achieved by irradiation of [Ru(tpy)(bpy)(DMF)](2+) (Ru-DMF2+; DMF = N,N-dimethylformamide) in a tetrahydrofuran (THF) solution containing excess triethylamine (NEW. The mechanism of the Ru-H+ formation was investigated in detail. A photochemical ligand substitution reaction of Ru-DMF2+ in THF proceeded to give [Ru(tpy)(bpy)(THF)](2+) (Ru-THF2+) with a quantum yield of (7.6 +/- 0.7) x 10(-2). In the presence of NEt3, a similar photochemical ligand substitution reaction also proceeded quickly, but the products were an equilibrium mixture of Ru-THF2+ and [Ru(tpy)(bpy)(NEt3)](2+) (Ru-NEt32+) with a considerable amount of Ru-H+ even in the first stage of the photochemical reaction. The equilibrium constant between Ru-THF2+ and Ru-NEt32+ was determined as 6.9 +/- 2.1. Irradiation to Ru-NEt32+ gave Ru-H+ with a quantum yield of (9.1 +/- 0.5) x 10(-3). An important intermediate, Ru-NEt32+, was isolated, and its properties were investigated in detail.

  DOI：

  10.1021/ic901080r