| 277306-09-9

• CAS: 277306-09-9
• 化学式: C₂₀H₂₇BrN₄Pt
• 分子量: 598.445
• InChiKey: SFHKNKOHOBFDAR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(Me)₂Pt(μ-SEt₂)]₂ 、 2-bromo-1,3-bis(3,5-dimethylpyrazol-1-ylmethyl)benzene 以 苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Facial and meridional [NCN]− intramolecular coordination systems: structure of fac-PtBrMe2{2,6-(pzCH2)2C6H3}·1/2C6H6 {[2,6-(pzCH2)2C6H3]−=2,6-(bis{(pyrazol-1-yl)methyl}phenyl)} and mer-PtBr{2,6-(3,5-Me2pzCH2)2C6H3}, and an alternative synthetic route to the platinum(II) [NCN]− kernel

  摘要：

  Intramolecular coordination by the six-membered monoanionic N,C,N chelating system 2,6-(pyrazol-1-ylmethyl)phenyl and substituted derivatives can give rise to facial and meridional coordination, exhibited by structural studies of facial. coordination in the platinum(IV) complex PtBrMe2{2,6-(pzCH(2))(2)C6H3}. 1/2C(6)H(6) and meridional coordination in the platinum(II) complex PtBr{2,6-(3,5-Me(2)pzCH(2))(2)C6H3} showing close to 'ideal' geometry for the [N-C-N](-) donor sets. A platinum(IV) complex is formed by oxidative addition of 2,6-(3,5-Me(2)pzCH(2))(2)C6H3Br to [PtMe2(SEt2)](2), but reaction with [Pt(p-Tol)(2)(SEt2)](2) gives the platinum(II) complex PtBr{2,6-(3,5-Me(2)pzCH(2))(2)C6H3} and 4,4'-bitolyl. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00763-9