| 228413-21-6

• CAS: 228413-21-6
• 化学式: C₃₃H₅₃AlN₂O₂
• 分子量: 536.778
• InChiKey: TWSAOJITYAVLPW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Syntheses and structures of products resulting from oxygen insertion and hydrolysis of Salan-Al compounds

  摘要：

  The combination of one and two equivalents of AlMe3 with the ligand, Salean(Bu-t)H-4 (N,N'-bis((3,5-di-tert-butyl)-2-hydroxybenzyl)-1,2-diamino ethane) leads to the compounds, Salean(Bu-t)H2AlMe (I), and Salean(Bu)HAlMe(AlMe2) (2). When 2 is exposed to air, [Salean(Bu-t)HAlOMe](2) (3) first forms, and then, after several days, [Salean(Bu-t)H2AlOH](2) (4). Compound 4 is the only product that occurs when 1 is exposed to air. All four compounds have been characterized by spectroscopic (IR,H-1 NMR, Al-27 NMR) and physical techniques (Mp, C,H analysis) and, in the case of 3 and 4, by X-ray crystallography. The structures consist of dimeric units with bridging OMe and OH groups. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00312-x
• 作为产物：
  描述：

  三甲基铝 、 N,N'-bis((3,5-di-tert-butyl)-2-hydroxybenzyl)-1,2-diaminoethane 以 甲苯 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Syntheses and structures of products resulting from oxygen insertion and hydrolysis of Salan-Al compounds

  摘要：

  The combination of one and two equivalents of AlMe3 with the ligand, Salean(Bu-t)H-4 (N,N'-bis((3,5-di-tert-butyl)-2-hydroxybenzyl)-1,2-diamino ethane) leads to the compounds, Salean(Bu-t)H2AlMe (I), and Salean(Bu)HAlMe(AlMe2) (2). When 2 is exposed to air, [Salean(Bu-t)HAlOMe](2) (3) first forms, and then, after several days, [Salean(Bu-t)H2AlOH](2) (4). Compound 4 is the only product that occurs when 1 is exposed to air. All four compounds have been characterized by spectroscopic (IR,H-1 NMR, Al-27 NMR) and physical techniques (Mp, C,H analysis) and, in the case of 3 and 4, by X-ray crystallography. The structures consist of dimeric units with bridging OMe and OH groups. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00312-x