(t)Bu4Al2(OCH2C6H4CH2OH)2 | 654084-99-8

• 英文名称: (t)Bu4Al2(OCH2C6H4CH2OH)2
• CAS: 654084-99-8
• 化学式: C₃₂H₅₄Al₂O₄
• 分子量: 556.741
• InChiKey: RACGHMKYCZCVDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (t)Bu3Al*OEt2 、 (t)Bu4Al2(OCH2C6H4CH2OH)2 以 甲苯 为溶剂， 以55%的产率得到(t)Bu5Al3(OCH2C6H4CH2O)2
  参考文献：
  名称：

  Binuclear alkylmetallane dioldiates tBu4M2(diol–(H))2 (M=Al, Ga) and their reactions with aluminium- and gallium trialkyls

  摘要：

  Reactions of 1,2-di(hydroxymethyl)benzene with (Bu3M)-Bu-t (M = Al, Ga) yield binuclear compounds [(Bu4M2)-Bu-t(OCH2C6H4-CH2OH)(2)], M = Al (1) and M = Ga (2) respectively. Compounds 1 and 2 as bifunctional (two OH groups), tetradentate (40) ligands react with aluminium- and gallium trialkyls with formation of trinuclear products [(Bu4XM3)-Bu-t(OCH2C6H4CH2O)(2)] [M = Al, X = Bu-t (3); M = Ga, X = Bu-t (4); M = Ga, X = Me (6)]. The transmetalation reaction of the compound 6 with one equivalent of Me3Ga causes the exchange of (Bu2Ga)-Bu-t unit and formation of the new mixed-ligand compound (Bu2Me3Ga3)-Bu-t(OCH2C6H4CH2O)(2) (7). The transmetalation reaction is considered as a method of synthesis of mixed-ligand and mixed-metal complexes of Group 13 alkyls with multidentate ligands. The molecular structures of Me5Al3(OCH2C6H4CH2O)(2) (5), 6 and 7 have been determined by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.018
• 作为产物：
  描述：

  邻苯二甲醇 、 (t)Bu3Al*OEt2 以 乙醚 为溶剂， 以79%的产率得到(t)Bu4Al2(OCH2C6H4CH2OH)2
  参考文献：
  名称：

  Binuclear alkylmetallane dioldiates tBu4M2(diol–(H))2 (M=Al, Ga) and their reactions with aluminium- and gallium trialkyls

  摘要：

  Reactions of 1,2-di(hydroxymethyl)benzene with (Bu3M)-Bu-t (M = Al, Ga) yield binuclear compounds [(Bu4M2)-Bu-t(OCH2C6H4-CH2OH)(2)], M = Al (1) and M = Ga (2) respectively. Compounds 1 and 2 as bifunctional (two OH groups), tetradentate (40) ligands react with aluminium- and gallium trialkyls with formation of trinuclear products [(Bu4XM3)-Bu-t(OCH2C6H4CH2O)(2)] [M = Al, X = Bu-t (3); M = Ga, X = Bu-t (4); M = Ga, X = Me (6)]. The transmetalation reaction of the compound 6 with one equivalent of Me3Ga causes the exchange of (Bu2Ga)-Bu-t unit and formation of the new mixed-ligand compound (Bu2Me3Ga3)-Bu-t(OCH2C6H4CH2O)(2) (7). The transmetalation reaction is considered as a method of synthesis of mixed-ligand and mixed-metal complexes of Group 13 alkyls with multidentate ligands. The molecular structures of Me5Al3(OCH2C6H4CH2O)(2) (5), 6 and 7 have been determined by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.018