[Ni(C6H4-o-C(O)CH3)(Cl)(dippe)] | 501364-41-6

• 英文名称: [Ni(C6H4-o-C(O)CH3)(Cl)(dippe)]
• CAS: 501364-41-6
• 化学式: C₂₂H₃₉ClNiOP₂
• 分子量: 475.642
• InChiKey: YOEOADFAGDIZJS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(C6H4-o-C(O)CH3)(Cl)(dippe)] 在 KO(C(CH₃)3) 作用下， 以 四氢呋喃 为溶剂， 以60%的产率得到[Ni(C6H4-o-C(O)(=CH2))(dippe)]
  参考文献：
  名称：

  Synthesis and Aldol Reactivity of O- and C-Enolate Complexes of Nickel

  摘要：

  The often facile C-/O-tautomerization of transition metal enolates is severely hindered in the cyclic Ni complexes 1 and 2, allowing the study of their individual reactivities. At room temperature only the O-bound tautomer, 2, reacts with aldehydes, giving rise to the corresponding addition products.

  DOI：

  10.1021/ja028711f
• 作为产物：
  描述：

  [(dippe)Ni(COD)] 、 alpha-氯乙酰苯 以 not given 为溶剂， 生成 [Ni(C6H4-o-C(O)CH3)(Cl)(dippe)]
  参考文献：
  名称：

  Synthesis and Aldol Reactivity of O- and C-Enolate Complexes of Nickel

  摘要：

  The often facile C-/O-tautomerization of transition metal enolates is severely hindered in the cyclic Ni complexes 1 and 2, allowing the study of their individual reactivities. At room temperature only the O-bound tautomer, 2, reacts with aldehydes, giving rise to the corresponding addition products.

  DOI：

  10.1021/ja028711f