Ethyl-i-propylthiocarbonyl-disulfid | 59937-91-6

• 英文名称: Ethyl-i-propylthiocarbonyl-disulfid
• 英文别名: ethylsulfanyl 2-methylpropanedithioate
• CAS: 59937-91-6
• 化学式: C₆H₁₂S₃
• 分子量: 180.359
• InChiKey: PGAYDSCTYILNNA-UHFFFAOYSA-N

物化性质

• 沸点：
  243.0±23.0 °C(Predicted)
• 密度：
  1.121±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.37
• 重原子数：
  9.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  S-ethyl p-toluenethiosulfonate 以51%的产率得到
  参考文献：
  名称：

  Lerivepend Catherine, Metzner Patrick, Tetrahedron Lett, 35 (1994) N 29, S 5229- 5230

  摘要：

  DOI：

文献信息

• THE PREPARATION AND REACTIONS OF UNSYMMETRICAL THIOCARBONYL DISULFIDES
  作者：Tomonori Katada、Sadaaki Tsuji、Tatsushi Sugiyama、Shinzi Kato、Masateru Mizuta

  DOI：10.1246/cl.1976.441

  日期：1976.5.5

  Unsymmetrical thiocarbonyl disulfides (3) have been easily synthesized in good yields by the reaction of piperidinium dithiocarboxylates with sulfenyl chlorides. In the reaction of these disulfides with nucleophiles (amine and metal alkoxide), both thiocarbonyl carbon and sulfenyl sulfur atom seem to be attacked by nucleophiles. By desulfurization with triphenylphosphine thiocarbonyl disulfides converted

  不对称硫代羰基二硫化物 (3) 可以通过哌啶鎓二硫代羧酸盐与亚磺酰氯的反应以良好的收率轻松合成。在这些二硫化物与亲核试剂（胺和金属醇盐）的反应中，硫代羰基碳和硫基硫原子似乎都被亲核试剂攻击。通过用三苯基膦硫代羰基二硫化物脱硫，以高产率转化为相应的二硫酯。
• Synthesis of sulfines by oxidation of trithioperesters and their rearrangement into acyltrisulfides
  作者：Catherine Leriverend、Patrick Metzner

  DOI：10.1016/s0040-4039(00)77070-5

  日期：1994.7

  Trithioperesters were synthesised by sulfenylation of halomagnesium alkanedithioates with alkylthiotoluenesulfonates and oxidised by mCPBA. The chemoselective conversion of a thiocarbonyl group into a sulfine moiety was achieved in three cases to yield the first examples of trithioperester sulfines. These compounds undergo at room temperature a novel rearrangement to acyltrisulfides.
• KATADA T.; TSUJI S.; SUGIYAMA T.; KATO S.; MIZUTA M., CHEM. LETT., 1976, NO 5, 441-444
  作者：KATADA T.、 TSUJI S.、 SUGIYAMA T.、 KATO S.、 MIZUTA M.

  DOI：——

  日期：——