[Co(2,6-bis(phenylmethyliminomethyl)-4-methylphenol(-H))2(N3)2]*MeOH | 1227010-24-3

• 英文名称: [Co(2,6-bis(phenylmethyliminomethyl)-4-methylphenol(-H))2(N3)2]*MeOH
• CAS: 1227010-24-3
• 化学式: CH₄O*C₄₆H₄₂Co₂N₁₀O₂
• 分子量: 916.934
• InChiKey: OLBTYTSCTUYBBW-UHLSTIFJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 cobalt(II) diacetate tetrahydrate 、 2,6-bis(N-benzylformimidoyl)-4-methylphenol 、 sodium azide 在 Et₃N 作用下， 以 甲醇 为溶剂， 以78%的产率得到[Co(2,6-bis(phenylmethyliminomethyl)-4-methylphenol(-H))2(N3)2]*MeOH
  参考文献：
  名称：

  Azido, Cyanato, and Thiocyanato Coordination Induced Distortions in Pentacoordinated [Co ^II A(bip)] ₂ (A = NCS ^– , N ₃ ^– , or NCO ^– ) Complexes

  摘要：

  AbstractA new family of distorted pentacoordinate [Co2] complexes was prepared and structurally characterized. In [CoIIA(bip)]2·S (1–3) [A = NCS–, N3–, NCO–; S = dmf, MeOH, dcm; Hbip = 2,6‐bis(phenylmethyliminomethyl)‐4‐methylphenol], the nonbonded Co···Co separations are in the 3.243 to 3.254 Å range, and the pseudohalide‐coordinated CoII ions are asymmetrically doubly bridged by the phenolate oxygen atoms of the ligand. The complementary basal–apical (b–a) and apical–basal (a–b) coordination modes of the phenolate bridges of bip– offer one O and two N donors for metal‐ion coordination. In the three dinuclear complexes, the h.s. CoII ions are coupled antiferromagnetically to yield a singlet ground state. The solid‐state variable‐temperature magnetic susceptibility measurement data on the complexes were fitted to an isotropic Heisenberg dimer model that allowed estimation of the antiferromagnetic interactions for 1–3. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900577