[(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2CH2PPh2)](OTf) | 246021-14-7

• 英文名称: [(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2CH2PPh2)](OTf)
• CAS: 246021-14-7
• 化学式: CF₃O₃S*C₃₆H₃₃FeP₂
• 分子量: 732.523
• InChiKey: QPZFATQRARHLGQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  trifluoromethanesulfonyloxy(triphenylphosphine)gold(I) 、 [(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2CH2PPh2)](OTf) 以 二氯甲烷 为溶剂， 以95%的产率得到[(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2CH2PPh2AuPPh3)](OTf)2
  参考文献：
  名称：

  Synthesis of gold ferrocenyl substituted ylides and methanides: crystal structure of [FcCH(AuPPh3)PPh3]ClO4 [Fc=(η5-C5H5)Fe(η5-C5H4)]

  摘要：

  The treatment of [FcCH(2)NMe(3)]I with tertiary or ditertiary phosphines gives the phosphonium salts [FcCH(2)PR(3)]I (PR3 = PPh3, PPh2Me) or [FcCH(2)PPh(2)CH(2)PPh(2)]I. The reaction of [FcCH(2)PR(3)]ClO4 with [Au(acac)(PPh3)] gives the ylide complexes [FcCH(AuPPh3)PR3]ClO4. The compound [FcCH(2)PPh(2)CH(2)PPh(2)]OTf reacts with several gold(I) complexes to give [FcCH(2)PPh(2)CH(2)PPh(2)(AuCl)]OTf, [FcCH(2)PPh(2)CH(2)PPh(2)(AuC6F5)]OTf or [FcCH(2)PPh(2)CH(2)PPh(2)(AuPPh3)](OTf)(2). The reaction of [FcCH(2)PPh(2)CH(2)PPh(2)]ClO4 with [O(AuPPh3)(3)]ClO4 leads to the methanide type species [FcCH(2)PPh(2)C(AuPPh3)(2)PPh2(AuPPh3)]-(ClO4)(2). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00038-9
• 作为产物：
  描述：

  (diphenylphosphinomethyl)(ferrocenylmethyl)diphenylphosphoniumiodide 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以78%的产率得到[(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2CH2PPh2)](OTf)
  参考文献：
  名称：

  Synthesis of gold ferrocenyl substituted ylides and methanides: crystal structure of [FcCH(AuPPh3)PPh3]ClO4 [Fc=(η5-C5H5)Fe(η5-C5H4)]

  摘要：

  The treatment of [FcCH(2)NMe(3)]I with tertiary or ditertiary phosphines gives the phosphonium salts [FcCH(2)PR(3)]I (PR3 = PPh3, PPh2Me) or [FcCH(2)PPh(2)CH(2)PPh(2)]I. The reaction of [FcCH(2)PR(3)]ClO4 with [Au(acac)(PPh3)] gives the ylide complexes [FcCH(AuPPh3)PR3]ClO4. The compound [FcCH(2)PPh(2)CH(2)PPh(2)]OTf reacts with several gold(I) complexes to give [FcCH(2)PPh(2)CH(2)PPh(2)(AuCl)]OTf, [FcCH(2)PPh(2)CH(2)PPh(2)(AuC6F5)]OTf or [FcCH(2)PPh(2)CH(2)PPh(2)(AuPPh3)](OTf)(2). The reaction of [FcCH(2)PPh(2)CH(2)PPh(2)]ClO4 with [O(AuPPh3)(3)]ClO4 leads to the methanide type species [FcCH(2)PPh(2)C(AuPPh3)(2)PPh2(AuPPh3)]-(ClO4)(2). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00038-9