[GeCl4(bis(dimethylamino)carbene)] | 1353847-03-6

• 英文名称: [GeCl4(bis(dimethylamino)carbene)]
• CAS: 1353847-03-6
• 化学式: C₅H₁₂Cl₄GeN₂
• 分子量: 314.566
• InChiKey: NCWGVOPCKSQAFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  germanium(II) chloride dioxane 、 双(二甲基氨基)二氟甲烷 以 四氢呋喃 为溶剂， 生成 [GeCl4(bis(dimethylamino)carbene)] 、 [GeF4(bis(dimethylamino)carbene)]
  参考文献：
  名称：

  Complexes of Ge(IV)- and Sn(IV)-Fluorides with Cyclic and Acyclic Carbenes: Bis(dialkylamino)-difluoromethylenes as Carbene Sources

  摘要：

  Carbene complexes of Ge(IV)- and Sn(IV)fluorides have been synthesized by oxidative addition of 2,2-difluoro-1,3-dimethylimidazolidine and bis(dimethylamino)difluoromethane to GeCl2 center dot dioxane and SnF2. Chloride analogs of the Ge(IV) complexes were also isolated. All compounds were characterized in the solid state by single-crystal X-ray diffraction.

  DOI：

  10.1021/ic202008m