| 578739-69-2

• CAS: 578739-69-2
• 化学式: C₄H₁₆B₁₀Cl₂O₄P₂
• 分子量: 369.132
• InChiKey: AWPVRWSGKUBUAP-FGZHOGPDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 甲苯 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  The first carboranyl bis(adenosine diphosphate) (CBADP): a synthetic investigation

  摘要：

  The synthesis of the first carboranyl bis(adenosine diphosphate) (CBADP) (5) was achieved in three steps. The first step involved the reaction of o-carborane dianion, 1, with methyl dichlorophosphate to yield 2. Reagent 4 was synthesized by the reaction of bis-benzoyl-protected adenosine with phosphoryl chloride, followed by the protection of the free hydroxyl group in the product, 3, with methyl triflate. The final step converged both 2 and 4 into the title compound, CBADP (5). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00067-4
• 作为产物：
  描述：

  1,2-dicarba-closo-dodecaborane(12) 、 二氯磷酸甲酯 以 甲苯 为溶剂， 以43%的产率得到
  参考文献：
  名称：

  The first carboranyl bis(adenosine diphosphate) (CBADP): a synthetic investigation

  摘要：

  The synthesis of the first carboranyl bis(adenosine diphosphate) (CBADP) (5) was achieved in three steps. The first step involved the reaction of o-carborane dianion, 1, with methyl dichlorophosphate to yield 2. Reagent 4 was synthesized by the reaction of bis-benzoyl-protected adenosine with phosphoryl chloride, followed by the protection of the free hydroxyl group in the product, 3, with methyl triflate. The final step converged both 2 and 4 into the title compound, CBADP (5). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00067-4