| 364635-13-2

• CAS: 364635-13-2
• 化学式: C₂₂H₂₄Cl₂N₄Ni
• 分子量: 474.055
• InChiKey: RNORPGNXENSWFD-IGXNNWCNSA-L

反应信息

• 作为产物：
  描述：

  邻苯二胺 、 乙酰丙酮 、 nickel(II) chloride hexahydrate 以 甲醇 为溶剂， 以66%的产率得到
  参考文献：
  名称：

  Metal Ion Directed Synthesis of 12 and 14-Membered Tetraaza Macrocyclic Complexes and their Physico-Chemical Studies

  摘要：

  The template condensation reaction of o-phenylenediamine with 2,3-butanedione or 2,4-pentanedione resulted in the formation of new series of 12 and 14-membered tetraaza macrocyclic complexes: [ML1 Cl-2], [ML2 Cl-2] [M=Co(II), Ni(II) and Zn(II)]; [CuL1] Cl-2 and [CuL2] Cl-2. The formation of the macrocyclic framework and the overall geometry of the complexes have been characterized by elemental analyses, FT-IR, (HNMR)-H-1, UV-Visible, magnetic susceptibility and conductivity measurements. The copper( II) complexes exhibit square planar geometry, whereas an octahedral geometry is suggested for all other complexes.

  DOI：

  10.1081/sim-200067064

文献信息

• Chandra; Gupta, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2001, vol. 40, # 7, p. 775 - 779
  作者：Chandra、Gupta

  DOI：——

  日期：——