(NH2C6H5N2C6H3CH3)(methanol)dichloridoiridium(III) | 1277125-58-2

• 英文名称: (NH2C6H5N2C6H3CH3)(methanol)dichloridoiridium(III)
• CAS: 1277125-58-2
• 化学式: C₁₄H₁₆Cl₂IrN₃O
• 分子量: 505.427
• InChiKey: ZBUOIVKEJLVVSY-JEEAYVPESA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (NH2C6H5N2C6H3CH3)(methanol)dichloridoiridium(III) 、 乙腈 以 乙腈 为溶剂， 以90%的产率得到(NH2C6H5N2C6H3CH3)(acetonitrile)dichloridoiridium(III)
  参考文献：
  名称：

  Reactions of 2-(arylazo)aniline with iridium trichloride: Synthesis, characterization and structure of new cyclometallated complexes of iridium(III)

  摘要：

  Reactions of 2-(arylazo)aniline, HL (H represents the dissociable protons upon orthometallation and HL is p-RC6H4N=NC6H4-NH2; R=H for HL1; CH3 for HL2 and Cl for HL3) with IrCl3 in methanol afforded ortho-metallated complexes of composition (L)(HL)IrCl2 (2) and (L)(MeOH)IrCl2 (3), respectively. Complex (L)(MeOH)IrCl2 (3) converted into (L)(CH3CN)IrCl2 (4) upon refluxing in acetonitrile. The X-ray structure of the complexes (L-1)(HL1)IrCl2 (2a) and (L-3)(CH3CN)IrCl2 (4c) have been determined and characterized unequivocally. The anionic L binds the metal in tridentate (C, N, N) manner for all the complexes. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.025
• 作为产物：
  描述：

  甲醇 、 氯化铱(III) 水合物 、 2-(4-methylphenylazo)aniline 以 甲醇 为溶剂， 以15%的产率得到(2-(p-tolylazo)aniline)(NH2C6H5N2C6H3CH3)dichloridoiridium(III)
  参考文献：
  名称：

  Reactions of 2-(arylazo)aniline with iridium trichloride: Synthesis, characterization and structure of new cyclometallated complexes of iridium(III)

  摘要：

  Reactions of 2-(arylazo)aniline, HL (H represents the dissociable protons upon orthometallation and HL is p-RC6H4N=NC6H4-NH2; R=H for HL1; CH3 for HL2 and Cl for HL3) with IrCl3 in methanol afforded ortho-metallated complexes of composition (L)(HL)IrCl2 (2) and (L)(MeOH)IrCl2 (3), respectively. Complex (L)(MeOH)IrCl2 (3) converted into (L)(CH3CN)IrCl2 (4) upon refluxing in acetonitrile. The X-ray structure of the complexes (L-1)(HL1)IrCl2 (2a) and (L-3)(CH3CN)IrCl2 (4c) have been determined and characterized unequivocally. The anionic L binds the metal in tridentate (C, N, N) manner for all the complexes. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.025