Si2Me4(2-methylindenyl)2ZrCl2 | 246167-99-7

• 英文名称: Si2Me4(2-methylindenyl)2ZrCl2
• CAS: 246167-99-7
• 化学式: C₂₄H₂₈Cl₂Si₂Zr
• 分子量: 534.787
• InChiKey: DJCWYTYVALLPMS-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [dimethyl-(2-methyl-1H-inden-1-yl)silyl]-dimethyl-(2-methyl-1H-inden-1-yl)silane 、 氯化锆(IV) 在 BuLi 、 Me₃SnCl 作用下， 以 甲苯 为溶剂， 以79.1%的产率得到Si2Me4(2-methylindenyl)2ZrCl2
  参考文献：
  名称：

  Si2Me4-bridged zirconocene dichlorides: crystal and molecular structure of meso-Si2Me4(3-SiMe3–C9H5)2ZrCl2

  摘要：

  A series of complexes Si2Me4L2ZrCl2 (L = Ind (Ib), 2-Me-Ind (2b), 3-SiMe3-Ind (3b) and Ind-H-4 (4)) was prepared. The syntheses of Ib, 3b and 4 gave predominantly the meso-isomers, whereas a 1:1 meso:rac mixture was obtained for 2b. X-ray analysis of meso-3b revealed large steric hindrance on the metal center (Cp degrees-Zr-Cp degrees is 134.6 degrees). The 1:1 mixture of meso-2b and rac-2b (activated with MAO) produced a 2.2:1 mixture of elastic atactic and isotactic polypropylene with low activity. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00184-9