| 345914-38-7

• CAS: 345914-38-7
• 化学式: C₂₂H₁₇ClMnN₄O*Cl
• 分子量: 479.247
• InChiKey: OFBKXTHWKMQEOO-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  吡啶-2-甲醛 、 2,2'-联吡啶 、 manganese(II) chloride tetrahydrate 、 2-氨基苯酚 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Oxidation of organic substrates catalyzed by novel mixed-ligand manganese(III) complexes

  摘要：

  Novel [Mn-III(amp)(bipy)(Cl)](1) (H(2)amp: N-(hydroxyphenyl)salicyldimine; bipy: 2,2'-bipyridyl) and [Mn-III(app)(bipy)-(Cl)](+) (2) (H(2)app: N-(hydroxyphenyl)pyridine-2- carboxaldimine; bipy: 2,2'-bipyridyl) complexes have been synthesized and characterized by physico-chemical methods. Complexes 1 and 2 have been employed as catalysts in the oxidation of both saturated and unsaturated hydrocarbons using tert-butylhydroperoxide (t-BuOOH). A mechanism involving formation of and transfer from a reactive highvalent Mn(V)-oxo species as catalytic intermediate is proposed for the catalytic processes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(00)00561-6