1-[chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12) | 202717-24-6

• 英文名称: 1-[chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)
• CAS: 202717-24-6
• 化学式: C₂₀H₂₅AuB₁₀ClP
• 分子量: 636.922
• InChiKey: XSMBSWNKFINRHD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12) 以 二氯甲烷 为溶剂， 以80%的产率得到1-[chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)
  参考文献：
  名称：

  1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

  摘要：

  The title compound, 1-[(C6H5)(2)PAuC1]-2-(C6H5)-1,2-closo-C2B10H10 or [AuC1{(C6H5)(2)P(C8H15B10)}], is the first reported derivative of 1-[(C6H5)2P]-2-(C6H5)1,2-closo-C2B10H10. The conformation of the cage phenyl group is comparable with the parent carbaborylphosphine, however, the (C6H5)(2)PAuCl substituent is less tilted from an idealized radial position on Cl due to a balance between two opposing sets of intramolecular forces. The P-Au-Cl fragment adopts the expected linear geometry.

  DOI：

  10.1107/s0108270197013048