[(η6-benzene)(5,6-diphenyl-3-(pyridine-2-yl)-1,2,4-triazine)chlororuthenium(II)] hexafluorophosphate | 936355-18-9

• 英文名称: [(η6-benzene)(5,6-diphenyl-3-(pyridine-2-yl)-1,2,4-triazine)chlororuthenium(II)] hexafluorophosphate
• CAS: 936355-18-9
• 化学式: C₂₆H₂₀ClN₄Ru*F₆P
• 分子量: 669.959
• InChiKey: WCCMGCLJKSVOOJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 [RuCl2(benzene)]2 、 3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪 以 甲醇 为溶剂， 以22%的产率得到[(η6-benzene)(5,6-diphenyl-3-(pyridine-2-yl)-1,2,4-triazine)chlororuthenium(II)] hexafluorophosphate
  参考文献：
  名称：

  Mononuclear arene ruthenium complexes containing 5,6-diphenyl-3-(pyridine-2-yl)-1,2,4-triazine as chelating ligand: Synthesis and molecular structure

  摘要：

  The mononuclear cations of the general formula [(eta(6)-arene)RuCl(pdpt)](+) (pdpt = 5,6-diphenyl-3-(pyridine-2-yl)-1,2,4-triazine; arene = C6H6 (1); C6H5Me (2); p-(PrC6H4Me)-C-i (3); C6Me6 (4)) have been synthesised from 5,6-diphenyl-3-(pyridine-2-yl)-1,2,4-triazine (pdpt) and the corresponding chloro complexes [(eta(6)-C6H6)Ru(mu-Cl)Cl](2), [(eta(6)-C6H5Me)Ru(mu-Cl)Cl](2), [(eta(6)p-(PrC6H4Me)-C-i)Ru(mu-Cl)Cl](2) and [(eta(6)-C6Me6) Ru(mu-Cl)Cl](2), respectively. The X-ray crystal structure analyses of [1][PF6] center dot (C6H6)(2.5) and [2][PF6] center dot (CH3CN)(2) reveal a typical piano-stool geometry around the metal centre and in the crystal packing a complexed networks of intermolecular interactions. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.11.007