Pb(C5Me4(i)Pr)2 | 228117-22-4

• 英文名称: Pb(C5Me4(i)Pr)2
• CAS: 228117-22-4
• 化学式: C₂₄H₃₈Pb
• 分子量: 533.766
• InChiKey: ZUQCSMBZRBLBCI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  LiC5Me4(i)Pr 、 lead(II) chloride 以 四氢呋喃 为溶剂， 以70%的产率得到Pb(C5Me4(i)Pr)2
  参考文献：
  名称：

  Synthesis and Characterization of Polyalkylated Pb(C₅Me₄R)₂ Plumbocenes, Including the X-ray Crystal Structure of Pb(C₅Me₄H)₂

  摘要：

  The reaction of 2 equiv of LiC5Me4R (R = H, Pr-i, Bu-n) with PbCl2 affords the Pb(C5Me4R)(2) metal-locenes in good yields. Pb((C5Me4Pr)-Pr-i)2 and Pb((C5Me4Bu)-Bu-n)(2) were isolated as red oils, while Pb(C5Me4H)(2) was isolated as an orange solid whose X-ray crystal structure reveals a bent-metallocene structure which has a 139.7 degrees (ring celitroid)-Pb-(ring centroid) angle.

  DOI：

  10.1021/om990064m