| 1052076-28-4

• CAS: 1052076-28-4
• 化学式: C₄₁H₄₁ClN₂P₂Ru
• 分子量: 760.26
• InChiKey: CWDXCHVEXOWVLN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 KO-tBu 作用下， 以 氘代苯 为溶剂， 生成 [RuH(diimP2)]
  参考文献：
  名称：

  Ruthenium hydrogenation catalysts with P–N–N–P ligands derived from 1,3-diaminopropane and the formation of a β-diiminate complex by a base-induced isomerization

  摘要：

  The complexes RuHCl{PPh2(2-C6H4)CH=NCH2CH2CH2N=CH(2-C6H4) PPh2} (RuHCl{prP(2)N(2)}, 7) and RuHCl{PPh2(2-C6H4) CH2NHCH2CH2CH2NHCH2(2-C6H4)PPh2} (RuHCl{prP(2)(NH)(2)}, 8) are prepared by reaction of RuHCl(PPh3)(3) with a ligand derived from 1,3- diaminopropane and ortho-diphenylphosphinobenzaldehyde. They are active precatalysts for the hydrogenation of acetophenone and are moderately active for the hydrogenation of benzonitrile and imines. The related complex RuHCl{ethP(2)(NH)(2)} with a ligand derived from 1,2-diaminoethane provides a more active catalyst. Complexes 7 and 8 undergo an unusual base-promoted isomerization reaction that produces a ruthenium complex containing a novel beta-diiminato ligand. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.12.003
• 作为产物：
  描述：

  hydridochlorotris(triphenylphosphine)ruthenium(II) 、 N, N'-bis[o-(diphenylphosphino)benzylidene]-1,3-diaminopropane 以 四氢呋喃 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  Ruthenium hydrogenation catalysts with P–N–N–P ligands derived from 1,3-diaminopropane and the formation of a β-diiminate complex by a base-induced isomerization

  摘要：

  The complexes RuHCl{PPh2(2-C6H4)CH=NCH2CH2CH2N=CH(2-C6H4) PPh2} (RuHCl{prP(2)N(2)}, 7) and RuHCl{PPh2(2-C6H4) CH2NHCH2CH2CH2NHCH2(2-C6H4)PPh2} (RuHCl{prP(2)(NH)(2)}, 8) are prepared by reaction of RuHCl(PPh3)(3) with a ligand derived from 1,3- diaminopropane and ortho-diphenylphosphinobenzaldehyde. They are active precatalysts for the hydrogenation of acetophenone and are moderately active for the hydrogenation of benzonitrile and imines. The related complex RuHCl{ethP(2)(NH)(2)} with a ligand derived from 1,2-diaminoethane provides a more active catalyst. Complexes 7 and 8 undergo an unusual base-promoted isomerization reaction that produces a ruthenium complex containing a novel beta-diiminato ligand. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.12.003