[μ-N-(((2,3-η1:η2)-4-methyl-2-thienyl)methyl)-η1:η1-(N)-p-xylylamino]hexacarbonyldiiron complex | 340146-74-9

• 英文名称: [μ-N-(((2,3-η1:η2)-4-methyl-2-thienyl)methyl)-η1:η1-(N)-p-xylylamino]hexacarbonyldiiron complex
• CAS: 340146-74-9
• 化学式: C₂₀H₁₅Fe₂NO₆S
• 分子量: 509.102
• InChiKey: FSSGFHJOTRGDOG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 N-(3-methyl-2-thienylmethylidene)-p-xylylamine 以 苯 为溶剂， 以22.4%的产率得到[μ-N-(((1,2-η1:η2)-p-tolyl)methyl)-η1:η1-(N)-p-xylylamino]hexacarbonyldiiron complex
  参考文献：
  名称：

  Ironcarbonyl complexes from N-(2-thienylmethylidene)benzylamines: endo as well as exo cyclometalation and alkyl exchange

  摘要：

  The reaction of methyl substituted N-(2-thienylmethylidene)benzylamine (1) with Fe-2(CO)(9) in benzene gives endo cyclometalated (mu-eta':eta (2)-thienyl; eta':eta'(N))hexacarbonyldiiron complexes (2 and 5), exo cyclometalated (mu-eta':eta (2)-phenyl;eta':eta'(N))hexacarbonyldiiron complexes (3 and 6) and/or imidoyl triironnonacarbonyl cluster (4), in accordance with the position of methyl substituent(s). In complex 3. the thienyl unit of the original Schiff base has been replaced by a phenyl group, which comes from the same Schiff base. The X-ray structure analyses were carried out on complexes 2a, 2b, 2c and 3a. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00616-1