[Pd(η3-(CH2C(CH3)CHCH3)(2,2'-bipyridyl)]ClO4 | 500305-58-8

• 英文名称: [Pd(η3-(CH2C(CH3)CHCH3)(2,2'-bipyridyl)]ClO4
• 英文别名: [Pd(η3-(CH2C(CH3)CHCH3)(bipy)]ClO4
• CAS: 500305-58-8；423719-22-6
• 化学式: C₁₅H₁₇N₂Pd*ClO₄
• 分子量: 431.184
• InChiKey: SVHACDZDYIOIJD-ZGVDEOGJSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 2-甲基-2-丁醇 、 tetraaqua palladium(II) perchlorate 在 高氯酸 作用下， 以 neat (no solvent) 为溶剂， 生成 [Pd(η3-(CH3)2CCHCH2)(2,2'-bipyridyl)]ClO4 、 [Pd(η3-(CH2C(CH3)CHCH3)(2,2'-bipyridyl)]ClO4
  参考文献：
  名称：

  摘要：

  Transformations of 2-methyl-2-propanol, 2-methyl-2-butanol, 2-methyl-2-pentanol, 1-methyl-1-cyclohexanol, and 1-ethyl-1-cyclohexanol in the presence of tetraaquapalladium(II) ions in perchloric acid madium were studied. It was found that the reactions give rise to palladium(II) pi-allyl complexes. The reaction rate increases and the yield of the corresponding pi-allyl complex decreases with increasing hydrocarbon chain length. Addition of iron(III) ions to the systems essentially increases the yield of palladium pi-allyl complexes. The olefin formed from the corresponding tertiary alcohol participates in the formation of the palladium pi-allyl complex. Oxidation of 2-methyl-2-butanol with tetraaquapalladium(II) ions gives the isomeric palladium pi-allyl complexes [Pd(eta(3)-(CH3)(2)CCHCH2)bpy]ClO4 and [Pd(eta(3)-(CH2C(CH3)CHCH3))bpy]ClO4, which were isolated using 2,2'-bipyridyl and characterized by H-1 and C-13 NMR spectroscopy.

  DOI：

  10.1023/a:1013244222139