di-μ-(3-methyl-2-thienylmethylideneamido)bis(tricarbonyliron) | 404576-21-2

• 英文名称: di-μ-(3-methyl-2-thienylmethylideneamido)bis(tricarbonyliron)
• CAS: 404576-21-2
• 化学式: C₁₈H₁₂Fe₂N₂O₆S₂
• 分子量: 528.129
• InChiKey: UKZFWKJBJVBHFE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 2-[2,3-diaza-4-(3-methyl-2-thienyl)buta-1,3-dienyl]-3-methylthiophene 以 正己烷 为溶剂， 以8.4%的产率得到di-μ-(3-methyl-2-thienylmethylideneamido)bis(tricarbonyliron)
  参考文献：
  名称：

  Iron carbonyl complexes from 2-[2,3-diaza-4-(2-thienyl)buta-1,3-dienyl]thiophene: NN bond cleavage and cyclometalation

  摘要：

  When thienyl Schiff base 1, derived from 2-formylthiophene and hydrazine, reacted with Fe-2(CO)(9) in n-hexane, three major complexes were obtained: (1) a diironhexacarbonyl complex with two 2-thienyhnethylideneamido bridging ligands 2, which resulted from the =N-N= bond cleavage of ligand 1; (2) a doubly cyclometalated di-mu -di-(eta (1):eta (2)-thienyl; eta (1):eta (1)(N))bis(hexacarbonyldiiron) complex (3); and (3) a cyclometalated (mu-eta (1):eta (2)-thienyl; eta (1):eta (1)(N))hexacarbonyldiiron complex (4). Molecular structures of compounds 1a, 1c, and 2a have been determined by single-crystal X-ray diffraction. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01188-3