(CO)5Cr=C(OMe)CH2CMe2CH=CH2 | 610271-62-0

• 英文名称: (CO)5Cr=C(OMe)CH2CMe2CH=CH2
• CAS: 610271-62-0
• 化学式: C₁₃H₁₄CrO₆
• 分子量: 318.247
• InChiKey: WIHIXWMVDNMKKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  potassium pentacarbonylchromate 、 3,3-dimethylpent-4-enoic acid chloride 、 三氟甲烷磺酸甲酯 以 not given 为溶剂， 生成 (CO)5Cr=C(OMe)CH2CMe2CH=CH2
  参考文献：
  名称：

  Coupling of Fischer Carbene Complexes with o-Alkynylbenzamides

  摘要：

  The coupling of 2-alkynylbenzamide derivatives with carbene complexes has been examined for systems that contain remote alkene functionality tethered either to the starting carbene complex or to the nitrogen of the amide. In most cases the reaction proceeds via alkyne insertion, followed by isobenzofuran formation, followed by intramolecular Diels-Alder reaction, followed by dehydration to afford aminonaphthalene derivatives. In examples using carbene complex tethered alkenes, intramolecular cyclopropanation is a competing reaction process.

  DOI：

  10.1021/om030383k