[Ru(benzonitrile)(diphenylphosphinoethane)(Cp*)][PF6] | 870543-71-8

• 英文名称: [Ru(benzonitrile)(diphenylphosphinoethane)(Cp*)][PF6]
• CAS: 870543-71-8
• 化学式: C₄₃H₄₄NP₂Ru*F₆P
• 分子量: 882.811
• InChiKey: RQMQGFBWWHZWIK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 pentamethylcyclopentadienyl(1,2-bis(diphenylphosphino)ethane)chlororuthenium(II) 、 苯甲腈 以 甲醇 为溶剂， 以78%的产率得到[Ru(benzonitrile)(diphenylphosphinoethane)(Cp*)][PF6]
  参考文献：
  名称：

  Syntheses and molecular structures of group 8 benzonitrile complexes

  摘要：

  The molecular structures of eight nitrite complexes of general form [M(NCC6H4R-4)(L-2)Cp']PF6 [M = Fe, Ru; L-2 = dppe, (PPh3)(2); Cp' = Cp Cp*] are reported and discussed in terms of the nature of the M-N interaction. Data are consistent with a predominantly a-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrite pi-back bonding interactions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.08.002