[[Ru(η3:η3-C10H16)(μ-Cl)Cl2](μ1,1'-bis(diphenylphosphino)ferrocene) | 402576-84-5

• 英文名称: [[Ru(η3:η3-C10H16)(μ-Cl)Cl2](μ1,1'-bis(diphenylphosphino)ferrocene)
• CAS: 402576-84-5
• 化学式: C₅₄H₆₀Cl₄FeP₂Ru₂
• 分子量: 1170.82
• InChiKey: QXZDOJWHLNQACX-QINWBEQCSA-J

反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II) 以 二氯甲烷 为溶剂， 以91%的产率得到[[Ru(η3:η3-C10H16)(μ-Cl)Cl2](μ1,1'-bis(diphenylphosphino)ferrocene)
  参考文献：
  名称：

  Reactivity of the bis(allyl)-ruthenium(IV) dimer [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] (C10H16=2,7-dimethylocta-2,6-diene-1,8-diyl) towards dppf (dppf=[Fe(η5-C5H4PPh2)2]) and dppfO (dppfO=[Fe(η5-C5H4PPh2)(η5-C5H4P(O)Ph2)])

  摘要：

  The bis(allyl)-ruthenium(IV) derivative [ Ru(eta (3):eta (3)-C10H16)(mu -Cl)Cl}(2)] reacts with dppf and dppfO to yield complexes [{Ru(eta (3):eta (3)-C10H16)Cl-2}(2)(mu -dppf)] and [Ru(eta (3):eta (3)-C10H16) Cl-2(kappa (1)-P-dppfO)], respectively. The electrochemical data of these complexes are reported. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00914-7