(2,5-norbornadiene)Pt(CD3)2 | 240123-30-2

• 英文名称: (2,5-norbornadiene)Pt(CD3)2
• CAS: 240123-30-2
• 化学式: C₉H₁₄Pt
• 分子量: 323.243
• InChiKey: UXALLEQJZWHTPQ-VJPXTNEWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,5-norbornadiene)Pt(CD3)2 、 N,N-dimethyl-2-diphenylphosphinoethylamine 以85%的产率得到[(κ(2)-P,N)-Me2NCH2CH2PPh2]Pt(CD3)2
  参考文献：
  名称：

  Transition Metal Silyl Complexes. 60.^,1 Enhanced Reactivity of a Platinum Dimethyl Complex toward Trimethoxysilane Due to a P,N-Chelating Co Ligand

  摘要：

  [(kappa(2)-P,N)-Me2NCH2CH2PPh2]PtMe2 reacts with trimethoxysilane to yield the methyl trimethoxysilyl complex [(kappa(2)-P,N)-Me2NCH2CH2PPh2]Pt[Si(OMe)(3)]Me, the bis(trimethoxysilyl) complex [(kappa(2)-P,N)-Me2NCH2CH2PPh2]Pt[Si(OMe)(3)](2), methyltrimethoxysilane, tetramethoxysilane, and small amounts of pentamethoxydisiloxane and hexamethoxydisiloxane. The formation of these compounds can be explained by Si-H oxidative addition/reductive elimination, as well as Si-O activation and scrambling reactions of the silicon substituents.

  DOI：

  10.1021/om990123w
• 作为产物：
  描述：

  二氯(去菠二烯)铂(II) 、 (Methyl-d3)magnesium iodide 以 乙醚 为溶剂， 以89%的产率得到(2,5-norbornadiene)Pt(CD3)2
  参考文献：
  名称：

  Transition Metal Silyl Complexes. 60.^,1 Enhanced Reactivity of a Platinum Dimethyl Complex toward Trimethoxysilane Due to a P,N-Chelating Co Ligand

  摘要：

  [(kappa(2)-P,N)-Me2NCH2CH2PPh2]PtMe2 reacts with trimethoxysilane to yield the methyl trimethoxysilyl complex [(kappa(2)-P,N)-Me2NCH2CH2PPh2]Pt[Si(OMe)(3)]Me, the bis(trimethoxysilyl) complex [(kappa(2)-P,N)-Me2NCH2CH2PPh2]Pt[Si(OMe)(3)](2), methyltrimethoxysilane, tetramethoxysilane, and small amounts of pentamethoxydisiloxane and hexamethoxydisiloxane. The formation of these compounds can be explained by Si-H oxidative addition/reductive elimination, as well as Si-O activation and scrambling reactions of the silicon substituents.

  DOI：

  10.1021/om990123w