{Ru(η2-C(CCC6H5)CHC6H5)(CO)2(P(C6H5)3)2} | 134290-01-0

• 英文名称: {Ru(η2-C(CCC6H5)CHC6H5)(CO)2(P(C6H5)3)2}
• CAS: 134290-01-0
• 化学式: C₅₄H₄₀O₂P₂Ru
• 分子量: 883.928
• InChiKey: KXQQKUKDYQHSEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Ru(η2-C(CCC6H5)CHC6H5)(CO)2(P(C6H5)3)2} 在 HClO₄ or HPF₆ 作用下， 以 二氯甲烷 为溶剂， 生成 {Ru(η3-C(CCC6H5)CHC6H5)(CO)2(P(C6H5)3)2}(1+)
  参考文献：
  名称：

  Reactions of α-phenylethynyl-trans-β-styryl complexes with isonitriles: hemi-labile alkyne coordination

  摘要：

  Treatment of the complex [Ru{C(C = CPh) = CHPh}Cl(CO)(PPh3)2] (1) with one equivalent of CNR (R = (t)Bu, C6H3Me2-2,6) gives [Ru{C(C = CPh) = CHPh}Cl(CNR)(CO)(PPh3)2]. Addition of a further equivalent of isonitrile and [NH4]PF6 leads to the salts [Ru{C(C = CPh) = CHPh}Cl(CNR)2(CO)(PPh3)2]PF6 and the mixed species [Ru{C(C = CPh) = CHPh}(CO)(CN(t)Bu)(CNC6H3Me2-2,6)(PPh3)2]PF6. The related [Ru{C(C = CPh)=CHPh}(CN(t)Bu)(CO)2(PPh3)2]PF6 is obtained by successive treatment of [Ru(CO)2(PPh3)3] with diphenylbutadiyne, hexafluorophosphoric acid and isonitrile or of 1 with carbon monoxide, AgPF6, and CN(t)Bu.

  DOI：

  10.1016/0022-328x(91)80092-x
• 作为产物：
  描述：

  {ruthenium(0) dicarbonyltris(triphenylphosphine)} 、 1，4-二苯基丁二炔 以 not given 为溶剂， 生成 {Ru(η2-C(CCC6H5)CHC6H5)(CO)2(P(C6H5)3)2}
  参考文献：
  名称：

  Reactions of α-phenylethynyl-trans-β-styryl complexes with isonitriles: hemi-labile alkyne coordination

  摘要：

  Treatment of the complex [Ru{C(C = CPh) = CHPh}Cl(CO)(PPh3)2] (1) with one equivalent of CNR (R = (t)Bu, C6H3Me2-2,6) gives [Ru{C(C = CPh) = CHPh}Cl(CNR)(CO)(PPh3)2]. Addition of a further equivalent of isonitrile and [NH4]PF6 leads to the salts [Ru{C(C = CPh) = CHPh}Cl(CNR)2(CO)(PPh3)2]PF6 and the mixed species [Ru{C(C = CPh) = CHPh}(CO)(CN(t)Bu)(CNC6H3Me2-2,6)(PPh3)2]PF6. The related [Ru{C(C = CPh)=CHPh}(CN(t)Bu)(CO)2(PPh3)2]PF6 is obtained by successive treatment of [Ru(CO)2(PPh3)3] with diphenylbutadiyne, hexafluorophosphoric acid and isonitrile or of 1 with carbon monoxide, AgPF6, and CN(t)Bu.

  DOI：

  10.1016/0022-328x(91)80092-x