[HC(C(t-Bu)(N(2,6-Me2C6H3)))2BPh2] | 1381803-48-0

• 英文名称: [HC(C(t-Bu)(N(2,6-Me2C6H3)))2BPh2]
• CAS: 1381803-48-0
• 化学式: C₃₉H₄₇BN₂
• 分子量: 554.627
• InChiKey: PIKKSWCBRGGCNZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(2,6-Me2C6H3)NC(t-Bu)CHC(t-Bu)N(2,6-Me2C6H3)]BCl2 、 苯基锂 以 甲苯 为溶剂， 生成 [HC(C(t-Bu)(N(2,6-Me2C6H3)))2BPh2]
  参考文献：
  名称：

  Cyclopropanation and Isomerization Reactions of β-Diketiminato Boron Complexes

  摘要：

  The reaction of HC[(CBut)(NAr)](2)Li with BCl3 yielded the azaallyl boron dichloride [ArN=C(Bu-t)C(H)C(Bu-t)-N(Ar)]BCl2 (1), which can be converted to the beta-diketiminato boron dichloride HC[(CBut)(NAr)](2)BCl2 (2) upon heating at 40 C. Reaction of 1 with the bulky lithium salts LiN(SiMe3)(2) and MesLi (Mes = 2,4,6-Me3C6H2) resulted in the cyclopropanation of the CBut group via the deprotonation of the methyl group, while reactions with PhLi and LiNEt2 gave substitution products.

  DOI：

  10.1021/om300337r