(pentamethylcyclopentadienyl)Co(2-pyridinethiolato)(4-pyridinethiolato) | 1059609-80-1

• 英文名称: (pentamethylcyclopentadienyl)Co(2-pyridinethiolato)(4-pyridinethiolato)
• 英文别名: Cp(*)Co(2-PyS)(4-PyS)
• CAS: 1059609-80-1
• 化学式: C₂₀H₂₃CoN₂S₂
• 分子量: 414.541
• InChiKey: ZBCMLXWDDSFOEX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶-4(1H)-硫酮 、 [Cp*Co(PyS)I] 在 n-C₄H₉Li 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以83%的产率得到(pentamethylcyclopentadienyl)Co(2-pyridinethiolato)(4-pyridinethiolato)
  参考文献：
  名称：

  Reactions of 2-pyridinethiolate cobalt(III) complexes with pyridinethiolate or benzenethiolate ligands

  摘要：

  Four half- sandwich cobalt complexes, Cp* Co( 2- PyS) 2 ( 2), Cp* Co( 2- PyS) 2 HI ( 3), Cp* Co( 2- PyS) ( 4- PyS) ( 4), ( Cp* Co) 2( l- PhS) 2( l- 2- PyS) I ( 5) [ Cp* = pentamethylcyclopentadienyl, 2- PyS = 2- pyridinethiolate, 4- PyS = 4- pyridinethiolate, PhS = benzenethiolate] were successfully synthesized by the reactions of 2- pyridinethione, lithium 4- pyridinethiolate and lithium benzenethiolate with Cp* Co( 2- PyS) I ( 1), respectively. Complexes 2 and 3 have the structures with two 2- pyridinethiolates ligands coordinated to the cobalt atom. Two different pyridinethiolates ligands can be identi. ed in complex 4. The molecular structure of 5 consists of two Cp* - Co fragments, which are triply bridged by three sulfur atoms from different ligands. The molecular structures of 3 and 5 were determined by X- ray crystallographic analysis. All the complexes have been well characterized by elemental analysis, NMR and IR spectra. (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.011