Ru(C(C2Ph)=CHPh)Cl(CO)(2,1,3-benzothiadiazole)(PPh3)2 | 861682-86-2

• 英文名称: Ru(C(C2Ph)=CHPh)Cl(CO)(2,1,3-benzothiadiazole)(PPh3)2
• 英文别名: [Ru(C(C.ident.CPh)=CHPh)Cl(CO)(2,1,3-benzothiadiazole)(PPh3)2]
• CAS: 861682-86-2
• 化学式: C₅₉H₄₅ClN₂OP₂RuS
• 分子量: 1028.56
• InChiKey: SYGPSPAHWBJLAA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(C(C2Ph)=CHPh)Cl(CO)(2,1,3-benzothiadiazole)(PPh3)2 、 α,α'-bis(dithiocarboxyoxy)-p-xylene potassium salt 以 甲醇 、 二氯甲烷 为溶剂， 以60%的产率得到[Ru(C(C2Ph)=CHPh)(CO)(PPh3)2]2(S2COCH2C6H4CH2COS2)
  参考文献：
  名称：

  基于羧酸盐和黄药的配体的双金属配合物：合成和电化学研究。

  摘要：

  同双金属钌（II）和（II）络合物[{RuR（CO）（PPh（3））（2）}（2）（S（2）COCH（2）C（6）H（4）CH（ 2）OCS（2））]（R = CH = CHBu（t），CH = CHC（6）H（4）Me-4，C（C [三键] CPh）= CHPh，CH = CHCPh（2） OH）和[{Os（CH = CHC（6）H（4）Me-4）（CO）（PPh（3））（2）}（2）（S（2）COCH（2）C（6） H（4）CH（2）OCS（2））]易于从[MRCl（CO）（BTD）（PPh（3））（2）]的反应中形成（M = Ru或Os; BTD = 2,1 ，3-苯并噻二唑）与双黄药KS（2）COCH（2）C（6）H（4）CH（2）OCS（2）K。KS（2）COCH（2）C（6）H（4）CH（2）OCS（2）K加至两个当量的顺式[RuCl（2）（dppm）（2）]导致形成[{（dp

  DOI：

  10.1039/b901822k

文献信息

• Dithiocarboxylate complexes of ruthenium(ii) and osmium(ii)
  作者：Saira Naeem、Amber L. Thompson、Andrew J. P. White、Lionel Delaude、James D. E. T. Wilton-Ely

  DOI：10.1039/c1dt10048c

  日期：——

  The ruthenium(II) complexes [Ru(R)(κ2-S2C·IPr)(CO)(PPh3)2]+ (R = CHCHBut, CHCHC6H4Me-4, C(CCPh)CHPh) are formed on reaction of IPr·CS2 with [Ru(R)Cl(CO)(BTD)(PPh3)2] (BTD = 2,1,3-benzothiadiazole) or [Ru(C(CCPh)CHPh)Cl(CO)(PPh3)2] in the presence of ammonium hexafluorophosphate. Similarly, the complexes [Ru(CHCHC6H4Me-4)(κ2-S2C·ICy)(CO)(PPh3)2]+ and [Ru(C(CCPh)CHPh)(κ2-S2C·ICy)(CO)(PPh3)2]+ are formed

  这 钌（II）配合物的[Ru（R）（κ 2 -S 2 C·IPR）（CO）（PPH 3）2 ] +（R = CH CHBu吨，CH CHC 6 H ^ 4 ME-4，C（C CPH）CHPh配合）是由IPr·CS 2与[Ru（R）Cl（CO）（BTD）（PPh 3）2 ] （电信发展局 = 2,1,3-苯并噻二唑）或[Ru（C（C CPh）CHPh）Cl（CO）（PPh 3）2 ]六氟磷酸铵。类似地，复合物的[Ru（CH CHC 6 H ^ 4 ME-4）（κ 2 -S 2 C·的ICy）（CO）（PPH 3）2 ] +及[茹（C（C CPH）CHPh配合）（κ 2当使用ICy·CS 2时，以相同的方式形成-S 2 C·ICy）（CO）（PPh 3）2 ] +。配体IMES·CS 2与[Ru（R）Cl（CO）（BTD）（PPh 3）2]，以形成所述化合物的[Ru（R）（κ 2 -S 2 C·IMES）（CO）（PPH
• Ruthenium hydride and vinyl complexes supported by nitrogen–oxygen mixed-donor ligands
  作者：James D.E.T. Wilton-Ely、Ming Wang、Sanaz J. Honarkhah、Derek A. Tocher

  DOI：10.1016/j.ica.2005.04.036

  日期：2005.7

  The Schiff base, 2-chlorophenylsalicylaldimine (HL1), is formed readily from salicylaldehyde and 2-chloroaniline. After deprotonation, this ligand is found to react as a bidentate mixed-donor chelate with the complexes [RuRCl(CO)(BTD)(PPh3)(2)] (R = H, CH=CHC6H5, CH=CHC6H4Me-4, CH=CH'Bu, CC CPh=CHPh; BTD = 2,1,3-benzothiadiazole) to form the compounds [RuR(L-1)(CO)(PPh3)(2)] through displacement of the chloride and BTD ligands. An analogous reaction occurs with the osmium complex [OsHCl(CO)(BTD)(PPh3)(2)] to provide [OsH(L-1)(CO)(PPh3)(2)]. The compound [Ru(CH=CHC6H4Me-4)(L-1)(CO)(PPh3)(2)] is formed through reaction of salicylalclehyde (HL2) with [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3)(2)] in the presence of base. Two further ligands were investigated to extend the study to encompass 5- and 4-membered chelates; 8-hydroxyquinoline (HL3) and 2-hydroxy-4-methylquinoline (HL4) react with [Ru(CH=CHPh)Cl(CO)(BTD)(PPh3)(2)] and [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3)(2)] in the presence of base to yield the complexes [Ru(CH=CHPh)(L-3)(CO)(PPh3)(2)] and [Ru (CH=CHC6H4Me-4)(L-4)(CO)(PPh3)(2)], respectively. The crystal structure of [Ru(CH=CHC6H4Me-4)(L-1)(CO)(PPh3)(2)] is reported. (c) 2005 Elsevier B.V. All rights reserved.