(hydrotris(3,5-dimethylpyrazolyl)borate)MoO2(NCS) | 90858-41-6

• 英文名称: (hydrotris(3,5-dimethylpyrazolyl)borate)MoO2(NCS)
• CAS: 90858-41-6
• 化学式: C₁₆H₂₂BMoN₇O₂S
• 分子量: 483.213
• InChiKey: AQVHBUAZXVJINW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (hydrotris(3,5-dimethylpyrazolyl)borate)MoO2(NCS) 在 (C₆H₅)3P 作用下， 以 二氯甲烷 为溶剂， 生成 {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}oxomolybdenum(V)(Cl)(NCS)
  参考文献：
  名称：

  Roberts, Sue A.; Young, Charles G.; Kipke, Cary A., Inorganic Chemistry, 1990, vol. 29, # 19, p. 3650 - 3656

  摘要：

  DOI：
• 作为产物：
  描述：

  三(3,5-二甲基-1-吡唑基)硼氢化钾 、 {Et4N}2{MoO2(NCS)4} 以 N,N-二甲基甲酰胺 为溶剂， 以62%的产率得到(hydrotris(3,5-dimethylpyrazolyl)borate)MoO2(NCS)
  参考文献：
  名称：

  Roberts, Sue A.; Young, Charles G.; Kipke, Cary A., Inorganic Chemistry, 1990, vol. 29, # 19, p. 3650 - 3656

  摘要：

  DOI：

文献信息

• Reaction of the tetrasulphidomolybdenum(IV) complex LMo(NCS)(S4) with dicarbomethoxyacetylene: X-ray structure of LMo(NCS){S2C2(CO2Me)2} [L = hydrotris(3,5-dimethylpyrazolyl)borate]
  作者：Aston A. Eagle、Charles G. Young、Edward R.T. Tiekink

  DOI：10.1016/s0277-5387(00)84208-4

  日期：1990.1

  The reaction of HB(Me2pz)3}Mo(NCS)(S4) [HB(Me2pz)3- = hydrotris(3,5-dimethylpyrazolyl)borate anion] with dicarbomethoxyacetylene in refluxing toluene results in the formation of the brown, diamagnetic complex HB9Me2pz)3}Mo(NCS)S2C2(CO2Me)2} (1) (the reactants above also yield 1 upon prolonged reaction in dichloromethane at 25-degrees-C), which has been characterized by X-ray crystallography. The mononuclear at 25-degrees-C), which has been characterized by X-ray crystallography. The mononuclear pseudo-octahedral complex contains a facially tridentate HB(Me2pz)3- ligand, a monodentate N-bound NCS- ligand, and a bidentate S2C2(CO2ME)2(2-) ligand having a near planar MoS2C4 fragment and A SC=CS bond distance of 1.342(15) angstrom. Solutions of 1 are unstable in air and decompose to produce HB(Me2pz)3}MoO2(NCS) and HB(Me2pz)3}MoO(NCS)2.
• Young, Charles G.; McInerney, Ian P.; Bruck, Michael A., Inorganic Chemistry, 1990, vol. 29, # 3, p. 412 - 416
  作者：Young, Charles G.、McInerney, Ian P.、Bruck, Michael A.、Enemark, John H.

  DOI：——

  日期：——