| 1547373-31-8

• CAS: 1547373-31-8
• 化学式: C₂₄H₄₀Cl₆Cu₄O₅S₄
• 分子量: 1003.74
• InChiKey: MVKCEXOQUZHWDZ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二烯丙基砜 、 copper(l) chloride 在 3-氯丙烯 作用下， 以Ca. 0.27 g的产率得到
  参考文献：
  名称：

  A crucial role of adamantanoid Cu(II) complexes in the redox systems: CuCl–diallylsulfoxide–O2 and CuCl2–diallylsulfide–O2

  摘要：

  The hypothetically reversible [Cu(I)(diallylsulfoxide)] <->(O2) [Cu(II)(diallylsulfide)] system was examined by FTIR spectroscopy and X-ray diffraction. It is stated that the Cu4OCl6 body centered adamantanoid cages, appearing at both the substrate and product sites, act as a template to promote the oxidation of diallylsulfide to diallylsulfoxide or Cu(I) to Cu(II), thus making the reaction irreversible. Each of these two adamantanoid cores possesses a different point symmetry as well as self assembly mode to form two polymorphs of the [Cu4OCl6(diallylsulfoxide)(4)] complex. Their polymorphic relationships based on the symmetry homology S-4 <- T-d -> C-3, as well as the distortion in the Cu(II) coordination geometry, are discussed. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.11.040