| 872104-50-2

• CAS: 872104-50-2
• 化学式: C₂₆H₃₉Ru*F₆P
• 分子量: 597.63
• InChiKey: WZSDSTMVKHFMRD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,2-di(pent-1-yn-1-yl)cyclohex-1-ene 、 tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate 以 丙酮 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  A Transition-Metal-Catalyzed Enediyne Cycloaromatization

  摘要：

  The pentamethylcyclopentadienyl iron cation, generated from [(eta5-C5Me5)Fe(NCMe)3]PF6, triggers the room temperature cycloaromatization of acyclic and alicyclic enediynes, in the presence of either 1,4-cyclohexadiene or terpinene as the hydrogen-atom donor, to give metal-arene products in good to excellent yields. Photolysis of the metal-arene complexes liberates the arene from the metal in excellent yield. The first demonstration of a transition-metal-catalyzed cycloaromatization of conjugated enediynes has been achieved under photochemical conditions utilizing either [(eta5-C5Me5)Fe(NCMe)3]PF6 or [(eta5-C5Me5)Fe(eta6-1,2-(Prn)2C6H4)]PF6 as the catalyst precursor. The use of a metal and light has led to a convenient method for cycloaromatization of a trans-enediyne.

  DOI：

  10.1021/ja050060a